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SUMMARY:AC Kolloquium - Dr. Alexander Hinz
DTSTART;TZID=Europe/Berlin:20241206T140000
DTEND;TZID=Europe/Berlin:20241206T150000
DTSTAMP:20260505T140835Z
UID:31db172351e14ef28b9438d2eb7eecc8@www.chemie.uni-bonn.de
CATEGORIES:ac-events,Lu-events
CREATED:20241129T095913Z
DESCRIPTION:Chemistry in confined spaces: Bulky carbazolides stabilise unu
 sual coordination environments\n\nThe use of sterically demanding substitu
 ents has allowed various developments in p-block chemistry\, such as synth
 esis of tetrylenes (silylenes\, germylenes\, stannylenes and plumbylenes) 
 which display unsual properties and reactivity. In these compounds\, the g
 roup 14 element is low-coordinated with coordination number 2. Driving thi
 s strategy to its logical conclusion\, the desired target for low-coordina
 ted compounds is coordination number 1 by involving even bulkier ligands. 
 To this end\, we developed a carbazole-based substituent (Cbz) and initial
 ly employed it in tetrylene chemistry. The synthesis and properties of low
 -coordinated group 14 compounds will be discussed in detail\, culminating 
 in the mono-coordinated silicon(II) cation [(Cbz)Si]+.
LAST-MODIFIED:20250906T002015Z
URL:https://www.chemie.uni-bonn.de/lu/de/lu-events/ac-kolloquium-dr-alexan
 der-hinz
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TZID:Europe/Berlin
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DTSTART:20241027T020000
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TZOFFSETFROM:+0200
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