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SUMMARY:Promotionskolloquium Timothy Michael Schwartz
DTSTART;TZID=Europe/Berlin:20251203T141500
DTEND;TZID=Europe/Berlin:20251203T151500
DTSTAMP:20260511T170330Z
UID:041380c940a54f3299165b3024cd68c9@www.chemie.uni-bonn.de
CATEGORIES:Lu-events,ac-events
CREATED:20251127T094849Z
DESCRIPTION:Synthesis Properties\, and Reactivity of Ni-Group 13 and Group
  14 Bimetallic Complexes\nTransition metal catalysts are essential for a v
 ariety of industrial catalytic applications. Earth-abundant transition met
 als have not replaced their precious metal counterparts partly because the
 y often undergo unproductive one-electron chemical reactions. To mitigate 
 this problem\, metal-ligand cooperativity has been used as an effective st
 rategy for controlling the reactivity of base metals. Lewis acidic metallo
 ligands are a particularly intriguing approach\, acting as σ-acceptors ca
 pable of stabilizing low-valent metal centers and promoting two-electron c
 hemistry. Using an optimized ligand scaffold featuring two unique binding 
 pockets\, a variety of Ni–group 13/14 heterobimetallic complexes were ex
 tensively studied. For these two types of compounds\, a comparison of the 
 synthesis\, various stabilizing bonding interactions\, and oxidative addit
 ion reactivity will be discussed.
LAST-MODIFIED:20251127T113914Z
URL:https://www.chemie.uni-bonn.de/lu/de/lu-events/promotionskolloquium-ti
 mothy-michael-schwartz
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DTSTART:20251026T020000
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TZOFFSETFROM:+0200
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