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Wissenschaftliche Meilensteine

Thema, Mitarbeiter/in, Publikationsnr., Jahr

First Dithia[2.2]phanes, F.V., 10, 1968
Steric interactions in the interior of cyclic compounds, F.V., 10, 1968
First sulfonepyrolysis -> phane, F.V., 20, 1969
Direct determination of spacial demand: Cl > CH3, I > Br, F.V., 21, 1969
"Circulus" magnetic stirrer, F.V., 15, 1969
First dynamic stereochemistry with [2.2]-and [3.3]phanes, F.V. 32, 16, 1969/1971
Firstly [2.2]meta and paracyclophanes by sulfonepyrolysis, F.V., 17, 20, 25, 1969/1970
First nomenclature of "phanes" P. Neumann, 30 (22), 1969/1970
First intraanular substituents F.V., 27, 1970
Firstly [3.3.3](1,3,5)cyclophane F.V., 26, 1970
"Superphane" proposed for [26](1,2,3,4,5,6)-cyclophane, P. Neumann, 39, 1972
Pyridin-N-oxide oxygen as intraanular group, Risler, 43, 1972
First 2- and 3-component high dilution apparatus, F.V., 37, 44, 1972
First one step threefold bridging Lichtenthaler, 49, 1973
Stereotemplate, I, F.V., 53, 1973
Stereotemplate 3D, Bunzel, VCH-publisher
Stencil "apparatus and devices", Bunzel, VCH-publisher
Stereoglasses, F.V., VCH-publisher
Mirror stereoscope, F.V., VCH-publisher
Drawing stencil, W.M. Müller, VCH-publisher
First degenerate diaza-cope rearrangement, Goldschmitt, 65, 91, 1974/1976
First Cope-rearrangement lecture and practical course experiment, Goldschmitt, 65, 1974
First pyridino-, thiopheno-, m-phenylene crowns, Weber, 64, 1974
Nonbenzylic sulfone pyrolysis, Grütze, 84, 1975
First open chain crown analogues ("podands"), Weber, 92, 1976
First tetraaryl-diaza-cope rearrangement Goldschmitt, Brombach 91, 121, 1976/1977
First drug crowns, Frensch, Jansen, Elben 98, 99, 131, 1976/1978
Double nonbenzylic sulfone pyrolysis, Rossa, 114, 1977
First phane-helix, Atzmüller, Wehner, Grütze, 102, 1977
First non-skid chain compounds, Wehner/Buhleier, 119, 1978
First repetitive synthesis (cascade synthesis), Wehner/Buhleier, 119, 1978
First dye crowns (uncharged chromoionophores), Dix, 149, 1978
First X-ray structure of open chain crown-urea-complex, Raßhofer, 135, 1978
First triphenylenicene-helix, Hammerschmidt,145, 1978
First cascade molecules (dendrimers), Buhleier, Wehner, 119, 1978
First ferroceno crowns, Oepen, 180, 1979
First continuous sulfone phyrolysis, Fornell, 192, 1979
First complex of g-cyclodextrin with crowns, cryptands and their M+-complexes, Müller, 191, 1979
First octopus compounds, Weber, 66, 1979
Firstly dimethylsulfate, hydrazine as guests in [18]crown-6, Müller, 201, 1980
First "stereologous" ligands, Leppkes, 216, 1981
First automatic 2- and 3-component high dilution principle apparatus, Karbach, Löhr, 230, 1981
First chloroform hosting host, Müller, 237, 1982
First one step four- and fivefold bridging, Klieser, 242, 1982
First onium-clathrates Löhr, 249, 260, 261, 1983
First [2.2]phane-helix Meurer, 257, 1983
First triphenylmethane-host (adamantane guest), Franke, 285, 1984
First hexapyridyl host, Müller, 279, 1984
First super siderand (Fe3+), Kiggen, 280, 1984
First semi conductor with macrocyclic structure/with TCNQ-replacement, Bunzel, 281, 1984
First liquid crystals with spiro-656-units/-646-units, Redlof, 287, 334, 1984
"Beautiful molecules"-article, Rossa, 315, 1985
First superhelix, Kißener, 295, 1985
First sixfold bridging in one step, Kißener, 311, 1985
First helical ligand (CuI) in the group, Thomeßen, 302, 1985
First chiral clathrates, Worsch, 325, 1986
First large ring driven C-Cope rearrangement, Eisen, 324, 1986
First super bipyridine siderand (Fe2+), Grammenudi (Thomeßen, Müller), 336, 1986
First electrochemically switchable hosts, Schrage, 328, 1986
First highly selective Ba2+-, Na+-ionophores, Kleiner/Bongardt/Prof. Simon, 303, 339, 1987
Amide catenanes/rotaxanes,  Maier, Händel, 455, 1992
C36H36, Seel, Groß, 440, 1992
Crowned Fullerenes, Osterodt, 472, 1993
Photoswitchable Catenanes, Müller, Bauer, Rissanen, 449, 508, 1993/1995
Ru-complexes, ET Frank, Prof. Balzani, De Cola, 477, 498, 1993/1994
Homocalixarenes, Brodesser, Schmitz, 503, 504, 1994
C60 X-ray of Wudl-adduct, Osterodt, 493, 1994
Molecular tubes/ribbons, belts, Schröder, Breidenbach, Ohren, Boomgaarden, Schwierz, 501, 513, 1994/1995
[3]rotaxanes, Dünnwald, 541, 1996
Rod-molecules, Nuding, 526, 1996
First pretzel compound, Händel, 543, 1996
Concave hydrocarbons, Groß, Harder, 560, 1996
C121, C122, Osterodt, 531, 1996
First cycloenantiomeric rotaxane (pure enantiomers), Schmidt, Prof. Okamoto, 575, 1997
First topologically chiral catenane, Schmidt, Prof. Okamoto, 575, 1997
Rotaxane assemblies, Dünnwald, Jäger, 574, 1997
Statistical synthesis of rotaxanes, Händel, Plevoets, 568, 1997
Dendritic bipyridines, Issberner, Plevoets, 567, 579, 1997/1998
Porphyrin-type wheels in rotaxanes, Ahuis, Prof. Sessler, 593, 1998
Geländer-Helices, Kiupel, 592, 1998
Chiral Azulenophanes, Mennicke, 602, 1999
Dendritic sensor materials, Windscheif, Hesse, 1999
Planar chiral bipy-catalysts, Wörsdörfer, 601, 1999
Pure pentaphenylenicene, Sobanski,1999
First cyclodiastereomeric [3]rotaxane, Schmieder, 624, 1999
Ether rotaxanes in quantitative yields, Hübner, Seel, 597, 1999
Dendritic Stoppering in Rotaxanes, Hübner, 637, 1999
Supramolecular dendrimers, Plevoets, Balzani, De Cola, 598, 642, 1999/2000
Molecular knots of the amide type, Safarowsky, Nieger, Fröhlich, 638, 2000
Chiral Induction into Dendrimer, Reuter, Pawlitzki, 648, 2000
Dendroknots, Recker, 676, 2002
Eosin-Guest in Dendrimer Hahn, Gorka, Balzani, 2002
Functionalized Knotanes, Dumbbell-Knot, Lukin, Recker, 2002
First Knotaxanes, Lukin, 2004
First Knotanophanes, Lukin, 2004
Dendron-substituted Salcomine, Portner, 2004

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