One
Wichtige Termine im Wintersemester 2017/2018
  • Beginn der Vorlesungszeit: 09.10.2017
  • Ende der Vorlesungszeit: 02.02.2018
  • Die Vorlesungen fallen aus: 23.12.2017 - 07.01.2018
  • Dies acdemicus: 06.12.2017
  • Feiertage: 31.10.2017, 01.11.2017
BIGS Chemistry

GDCh Ortsverband Bonn

 

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Vorsitzender: Prof. Dr. A. Lützen
Jungchemikerforum Bonn


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KOPO 2017

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Ansprechpartner
Prof. Dr. A.C. Filippou
Institut für Anorganische Chemie
Gerhard-Domagk-Str. 1
Tel: 0228/73-2700
Fax: 0228/73-5327
 
Sie sind hier: Startseite Veranstaltungen Dr. Fabian Dielmann (Universität Münster): Superbasic Phosphines: New Prospects for Small Molecule Activation and Catalysis

Termin: 23.11.2017 Uhrzeit: 17:15 - 19:00 ( Donnerstag )

Dr. Fabian Dielmann (Universität Münster): Superbasic Phosphines: New Prospects for Small Molecule Activation and Catalysis

AC Kolloquium
Referent/in: Dr. Fabian Dielmann
Inhalt:

Tertiary phosphines (PR3) are a fascinating and versatile class of compounds that have found wide applications as organocatalysts and as ligands in organometallic chemistry. Because of their remarkable electronic and steric tunability, phosphines have the ability to profoundly modulate the the steric and electronic properties of metal complexes to which they’re bound. We recently reported a new approach to expand the accessible stereoelectronic properties of phosphines beyond their classical boundaries by directly attaching imidazolin-2-ylidenamino groups to the phosphorus atom. The resulting superbasic phosphines can be powerful ligands in homogeneous catalysis and they can activate and transform small molecules such as CO2, SO2, N2O and P4. The new phosphine’s properties and their potential to act as (cooperative) ligand will be discussed. Examples for their reactivity and applications in catalysis will be provided.

Öffentliche Veranstaltung: Ja
Ort: Chemische Institute
Adresse: Gerhard-Domagk-Str. 1
Raum: HS 2
Veranstalter: Institut für Anorganische Chemie
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