Publications
2025
25. P. Palui, M. Bollenbeck, D. Meleschko, P. Brehm, R. M. Gomila, G. Schnakenburg, A. Frontera, A. Bismuto.
Azadistibiridines and stabilised-iminobismuthane: reactivity of small inorganic rings in heavy main group chemistry.
Chem. Sci., 2025, 16, 16894-16903.
DOI: https://doi.org/10.1039/D5SC03416G
24. A. Korzun, M. J. McKee, H. Neugebauer, O. Green, G. Schnakenburg, S. Grimme, N. Kornienko, A. Bismuto.
Antimony and Bismuth Complexes as Visible Light Photosensitizers in Catalytic Oxidation Reactions.
Inorg. Chem., 2025, 64, 30, 15667–15679.
DOI: https://doi.org/10.1021/acs.inorgchem.5c02152
23. P. Palui, S. Ghosh, R. M. Gomila, G. Schnakenburg, A. Frontera, A. Bismuto.
Combining Distibene, Diazoolefins, and Visible Light: Synthesis and Reactivity of Inorganic Rings.
J. Am. Chem. Soc., 2025, 147, 2, 1421–1426.
DOI: https://doi.org/10.1021/jacs.4c15626
2024
22. D. Meleschko, P. Palui, G. Pugliese, G. Schnakenburg, R. M. Gomila, A. Frontera, A. Bismuto.
Synthesis, Reactivity, and Theoretical Insights of Co-Sb2 and Co-Bi2 Rings.
Organometallics, 2024, 43, 20, 2581–2588.
DOI: https://doi.org/10.1021/acs.organomet.4c00238
21. D. Meleschko, P. Palui, R. M. Gomila, G. Schnakenburg, A. C. Filippou, A. Frontera, A. Bismuto
Light-Dependent Reactivity of Heavy Pnictogen Double Bonds.
Angew. Chem. Int. Ed., 2024, 63, e202405400.
DOI: https://doi.org/10.1002/anie.202405400
2023
20. P. Müller, P. Finkelstein, N. Trapp, A. Bismuto, G. Jeschke, B. Morandi.
Nickel (I)–Phenolate Complexes: The Key to Well-Defined Ni (I) Species.
Inorganic Chemistry, 2023, 62, 16661-16668.
DOI: https://doi.org/10.1021/acs.inorgchem.3c01559
19. A. Korzun, S. Crespi, C. Golz, A. Bismuto
Replacing the BO in BODIPY: unlocking the path to SBDIPY and BIDIPY chromophores.
Chem. Sci., 2023, 14, 6579-6584.
DOI: https://doi.org/10.1039/D3SC01493B
2022-2018
18. M. Bogdos, O. Stepanovic, A. Bismuto, M. Luraschi, B. Morandi.
Mechanistically informed selection rules for competing β-hydride and β-heteroatom eliminations.
Nature Synthesis, 2022, 10, 787-793.
DOI: https://doi.org/10.1038/s44160-022-00145-x
17. A. Bismuto, P. Müller, P. Finkelstein, B. Morandi.
The journey of Ni(I) Chemistry.
Helv. Chim. Acta, 2021, 104, e2100177.
DOI: https://doi.org/10.1002/hlca.202100177
16. A. Bismuto, P. Müller, P. Finkelstein N. Trapp, G. Jeschke, B. Morandi.
One to find them all: a general route to Ni(I) phenolate species.
J. Am. Chem. Soc., 2021, 143, 10642-10648.
DOI: https://doi.org/10.1021/jacs.1c03763
15. L. Huang, A. Bismuto, S.A. Rath, N. Trapp, B. Morandi.
Ruthenium‐catalyzed Dehydrogenation Through an Intermolecular Hydrogen Atom Transfer Mechanism.
Angew. Chem. Int. Ed., 2021, 60, 7336-7372.
DOI: https://doi.org/10.1002/ange.202015837
14. P. Boehm, S. Roediger, A. Bismuto, B. Morandi.
Palladium-catalyzed Chlorocarbonylation of Aryl Halides Through in situ Generation of Carbon Monoxide.
Angew. Chem. Int. Ed., 2020, 132, 17887-17896.
DOI: https://doi.org/10.1002/anie.202005891
13. A. Bismuto, T. Delcaillau, P. Müller, B. Morandi.
Nickel-catalyzed Amination of Aryl Thioethers: A Combined Synthetic and Mechanistic Study.
ACS Catalysis, 2020, 10, 4630-4639.
DOI: https://doi.org/10.1021/acscatal.0c00393
12. P. Yu, A. Bismuto, B. Morandi.
Iridium-Catalyzed Hydrochlorination and Hydrobromination of Alkynes by Shuttle Catalysis.
Angew. Chem. Int. Ed., 2020, 59, 2904-2910.
DOI: https://doi.org/10.1002/anie.201912803
11. T. Delcaillau, A. Bismuto, Z. Lian, B. Morandi.
Nickel-Catalyzed Inter- and Intramolecular Aryl Thioether Metathesis by Reversible Arylation.
Angew. Chem. Int. Ed., 2020, 59, 2110-2114.
DOI: https://doi.org/10.1002/anie.201910436
10. A. Bismuto, M. J. Cowley, S. P. Thomas.
Zwitterion-initiated hydroboration of alkynes and styrenes.
Adv. Synth. Catal., 2021, 363, 2382-2385.
DOI: https://doi.org/10.1002/adsc.202001323
9. A. Bismuto, G. S. Nichol, F. D. Gonzalez, M. J. Cowley, S. P. Thomas.
Characterization of the zwitterionic intermediate in 1,1-carboboration of alkynes.
Angew. Chem. Int. Ed., 2020, 59, 12731-12735.
DOI: https://doi.org/10.1002/anie.202003468
8. M. W. Stanford, A. Bismuto, M. J. Cowley.
Silyl Anion Initiated Hydroboration of Aldehydes and Ketones.
Chem. Eur J., 2020, 26, 9855-9858.
DOI: https://doi.org/10.1002/chem.202000897
7. R. J. Oeschger, M. A. Larsen, A. Bismuto, J. F. Hartwig.
Origin of the Difference in Reactivity between Ir Catalysts for the Borylation of C–H Bonds.
J. Am. Chem. Soc., 2019, 41, 16479-16485.
DOI: https://doi.org/10.1021/jacs.9b08920
6. A. Bismuto, M. J. Cowley, S. P. Thomas.
Aluminum-catalyzed hydroboration of alkenes.
ACS Catalysis, 2018, 8, 2001-2005.
DOI: https://doi.org/10.1021/acscatal.7b04279
5. N. W. J. Ang, C. S. Buettner, S. Docherty, A. Bismuto, J. R. Carney, J. H. Docherty, M. J. Cowley, S. P. Thomas.
Borane-catalyzed hydroboration of alkynes and alkenes.
Synthesis, 2017, 50, 803-808.
DOI: https://doi.org/10.1055/s-0036-1591719
4. A. Bismuto, S. P. Thomas, M. J. Cowley.
Aluminum hydride catalyzed hydroboration of alkynes.
Angew. Chem. Int. Ed., 2016, 55, 15356-15359.
DOI: https://doi.org/10.1002/anie.201609690
3. E. Marelli, M. Corpet, Y. Minenkov, R. M. Neyyappadath, A. Bismuto, G. Buccolini, M. Curcio, L. Cavallo, S. P. Nolan.
Catalytic α-arylation of imines leading to N-unprotected indoles and azaindoles.
ACS Catalysis, 2016, 6, 2930-2938.
DOI: https://doi.org/10.1021/acscatal.6b00040
2. A. Bismuto, M. E. Cucciolito, F. Ruffo, A. Vitagliano, M. Curcio.
Mild, Selective and Efficient Oxidation of Sulfides to Sulfoxides Catalyzed by Mn(III)-Salen Complexes.
Phosphorus, Sulfur, and Silicon and the Related Elements, 2015, 190, 1021-1028.
DOI: https://doi.org/10.1080/10426507.2014.952005
1. F. Ruffo, A. Bismuto, A. Carpentieri, M. E. Cucciolito, M. Lega, A. Tuzi.
The elpaN-salen series: multifunctional ligands for the Mn (III)-catalyzed enantioselective epoxidation of styrenes.
Inorg. Chim. Acta, 2013, 405, 288-294.
DOI: https://doi.org/10.1016/j.ica.2013.06.007