Sadeep Kumar: Low-Valent Heavier Tetrel Compounds Supported by N-heterocyclic Carbenes: A Comprehensive Experimental and Theoretical Perusal 2-tetrelavinylidenes (C=EH2; E = Si, Ge) are according to quantum chemical studies the least stable isomers on the [E,C,2H] potential energy hypersurface isomerizing easily via the trans-bent tetrelaacetylenes HE≡CH to the thermodynamically most stable 1-tetrelavinylidenes (E=CH2).
Giacomo Puglise: Homogeneous catalysis is an essential tool for organic synthesis, which allows synthetic chemists to draw new and efficient disconnections for the manufacture of drugs and agrochemicals.