AK Streubel
© P. Brehm
AK Streubel
© R. Streubel
AK Streubel
AK Streubel

Highlighted Publikationen:

  1. R. Streubel: Transient Nitrilium Phosphanylid Complexes - New Versatile Building Blocks in Phosphorus Chemistry, Top. Curr. Chem. 2002, 223, 91-109.
  2. R. Streubel: Chemistry of λ3-2H-azaphosphirene Metal Complexes, Coord. Chem. Rev. 2002 227, 175-192.
  3. R. Streubel: 1λ5-Phosphinines, Science of Synthesis 2005, Vol- 15, 1157-1179.
  4. T. Sasamori, N. Tokitoh, R. Streubel, pi-Electron Redox Systems of Heavier Group 15 Elements, in Organic Redox Systems, Synthesis, Properties and Applications (ed. T. Nishinaga), Wiley, hoboken, New Jersey, 2016, 563-578.
  5. N. Volk, P. Malik, A. Garcia Alcaraz, A. Espinosa Ferao, R. Streubel, Chemistry of oxaphosphirane complexes, Coord. Chem. Rev. 2021, 437, 213818.
  6. A. Schmer, P. Junker, A. Espinosa Ferao, R. Streubel, M/X Phosphinidenoid Metal Complex Chemistry, Acc. Chem. Res. 2021, 54, 1754-1765.
  7. A. Garcia Alcaraz, A. Espinosa Ferao, R. Streubel, Azaphosphiridines: Challenges and perspectives, Dalton Trans. 2021, 50, 7324-7336.
  8. D. Welideniya, M. Ramachandran, T. Kalisch, R. Streubel, New frontiers: 1,4-diphosphinines and P-bridged bis(NHCs), Dalton Trans. 2021, 50, 9345-9366. DOI: 10.1039/d1dt01624e
  9. P. Brehm, A. Frontera, R. Streubel, On metal coordination of neutral open-shell P-ligands focusing on phosphanoxyls, their electron residence and reactivity, Chem. Commun. 2022, 58, 6270-6279. DOI: 10.1039/D2CC01302A
  10. D. Biskup, G. Schnakenburg, R. T. Boére, A. Espinosa Ferao, R. K. Streubel, Challenging an old paradigm by demonstrating transition metal-like chemistry at a neutral nonmetal center, Nat.Commun. 2023, 14, 6456. DOI: 10.1038/s41467-023-42127-3

Publikationen in chronologischer Reihenfolge:

  1. E. Niecke, R. Streubel, M. Nieger, D. Stalke, Synthese und Struktur eines 1H-Diphosphirens, Angew. Chem. 1989, 101, 1708-1710; Angew. Chem. Int. Ed. Engl. 1989, 28, 1673-1674.
  2. E. Niecke, H. J. Metternich, R. Streubel, Diphosphabicyclobutane, Chem. Ber. 1990, 123, 67-69.
  3. R. Streubel, E. Niecke, Halogen(silyl)phosphane - Synthese und Eigenschaften, Chem. Ber. 1990, 123, 1245-1251.
  4. E. Niecke, R. Streubel, M. Nieger, trans-1.2.4.5.-Tetraphosphatricyclo(3.1.0.0.2.4)hexan durch [2+2]-Cyclodimeri-sierung eines 3H-Diphosphirens, Angew. Chem. 1991, 103, 103-105; Angew. Chem. Int. Ed. Engl. 1991, 30, 90-91.
  5. R. Streubel, E. Niecke, P. Paetzold, Azaphosphaboriridine und Azadiphosphiridine durch Phosphandiyl-Transfer, Chem. Ber. 1991, 124, 765-767.
  6. R. Streubel, E. Niecke, M. Nieger, Three-membered Phosphorus Heterocycles by Phosphanediyl-Transferreactions, Phosphorus Sulfur Relat. Elem. 1992, 65, 115-118.
  7. R. Streubel, E. Niecke, M. Nieger, Synthese, Struktur und Eigenschaften von Diphosphirane ,Chem. Ber. 1993, 126, 645-648.
  8. R. Streubel, N. H. T. Huy, L. Ricard, F. Mathey, Phosphametallacyclobutane- and Phosphametallacyclobutene-Derivatives by Insertion Reaction, Phosphorus Sulfur Relat. Elem. 1993, 77, 229.
  9. R. Streubel, N. H. T. Huy, F. Mathey, The Reaction of Terminal Phosphinidene Complexes with Phosphaalkenes. Thermal Symmetrisation of Diphosphiranes with Asymmetric Substitution Patterns, Synthesis 1993, 763-764.
  10. R. Streubel, M. Frost, M. Nieger, E. Niecke, 1,2-Dihydro-1,3-diphosphetes by cyclocodimerization between phosphaalkynes and phosphaalkenes, Bull. Soc. Chim. Fr. 1993, 130, 642-646.
  11. R. Streubel, J. Jeske, P. G. Jones, R. Herbst-Irmer, Synthesis of the first 2H-Azaphosphirene Complexes, Angew. Chem. 1994, 106, 115-117; Angew. Chem. Int. Ed. Engl. 1994, 33, 80-82.
  12. R. Streubel, A. Kusenberg, Synthesis, Structure and Reactions of 2H-Azaphosphirene Derivatives, Phosphorus Sulfur Relat. Elem. 1994, 93-94, 281-284.
  13. R. Streubel, M. Hobbold, J. Jeske, P. G. Jones, P-H-functionalized-Ylide-Carbene Complexes: Synthesis of [(CO)5M=C(OEt) CH=P(NiPr2)2H] (M = Cr, W) and Structure of the Chromium Derivative, J. Chem. Soc., Chem. Commun. 1994, 2457-2458.
  14. R. Streubel, A. Kusenberg, J. Jeske, P. G. Jones, Thermisch-induzierte Ringspaltung eines 2H-Azaphosphiren-Wolframkomplexes, Angew. Chem. 1994, 106, 2564-2566; Angew. Chem. Int. Ed. Engl. 1994, 33, 2427-2428.
  15. R. Streubel, Phosphaalkin-Cyclooligomere: von Dimeren zu Hexameren - erste Schritte auf dem Weg zu Phosphor-Kohlenstoff-Käfigverbindungen, Angew. Chem. 1995, 107, 478-480; Angew. Chem. Int. Ed. Engl. 1995, 34, 436-438.
  16. R. Streubel, Phosphorus-31 NMR Spectral Properties in Compound Characterization and Structural Analysis, Angew. Chem. 1995, 107, 1918-1919; Angew. Chem. Int. Ed. Engl. 1995, 34, 1651-1653 (Rezension).
  17. R. Streubel, L. Ernst, J. Jeske, P. G. Jones, Synthesis and Structure of the first trans-1,2-Dihydro-1,2,3-triphosphete-Tungsten Complex, J. Chem. Soc., Chem. Commun. 1995, 2113-2114.
  18. A. Ostrowski, J. Jeske. P. G. Jones, R. Streubel, Easy Access to C,C'-Bifunctionalized 1H-Phosphirene-Tungsten Complexes: Evidence for Ambiphilic Reaction Behaviour of a Phosphanediyl-Tungsten Complex, J. Chem. Soc., Chem. Commun. 1995, 2507-2508.
  19. R. Streubel, A. Ostrowski, Recent Results on Synthesis and Ring Cleavage Reactions of 2H-azaphosphirene Derivatives, Phosphorus Sulfur Relat. Elem. 1996, 109-110, 153-156.
  20. R. Streubel, M. Hobbold, J. Jeske, F. Ruthe, P. G. Jones, Synthese und Strukturen von N-Bis(diisopropylamino)phosphanyl-substituierten Aminocarbenkomplexen der Metalle Chrom, Molybdän und Wolfram, J. Organomet. Chem. 1997, 529, 351-356.
  21. R. Streubel, A. Ostrowski, H. Wilkens, F. Ruthe, J. Jeske, P. G. Jones, Überraschende intramolekulare Folgereaktionen intermediärer Phosphacarbonyl-Ylid-Wolframkomplexe, Angew. Chem. 1997, 109, 409-413; Angew. Chem. Int. Ed. Engl. 1997, 36, 378-381.
  22. R. Streubel, M. Hobbold, J. Jeske, P. G. Jones, Stereoselektive Synthese und Valenzisomerisierung von1-2-Phosphabutadien-Komplexen zu 1-2,3-Dihydrophosphet-Komplexen, Angew. Chem. 1997, 109, 1131-1133; Angew. Chem. Int. Ed. Engl. 1997, 36, 1095-1097.
  23. R. Streubel, H. Wilkens, A. Ostrowski, C. Neumann, F. Ruthe, P. G. Jones, Bildung von 2H-1,2-Azaphosphol-Wolframkomplexen durch Abfangreaktion von Nitriliumphosphan-Ylid-Komplexen, Angew. Chem. 1997, 109, 1549-1550; Angew. Chem. Int. Ed. Engl. 1997, 36, 1492-1493.
  24. R. Streubel, The Natural Selection of the Chemical Elements, Nachr. Chem. Tech. Lab. 1997, 45, 1014-1015 (book review).
  25. M. Hobbold, R. Streubel, M. H. A. Benvenutti, P. B. Hitchcock, J. F. Nixon, Syntheses and Structures of ( 4-2-Phosphabutadiene)tricarbonyliron Complexes, Organometallics 1997, 16, 3726-3728.
  26. A. Ostrowski, J. Jeske, F. Ruthe, P. G. Jones, R. Streubel, Synthese und spektroskopische Charakterisierung einiger Pentacarbonylwol-fram(0)-Komplexe mit verschiedenen 1H-Phosphiren-Liganden, Kristallstrukturen von [{(Me3Si)2HCPC(H)=CPh}W(CO)5], [{(Me3Si)2HCPC(CH3)=CPh}W(CO)5] und [{(Me3Si)2HCPC(COOEt)=CPh}W(CO)5], Z. Anorg. Allg. Chem. 1997, 623, 1897-1902.
  27. H. Wilkens, J. Jeske, P. G. Jones, R. Streubel, Synthesis and Structure of the First 2H-1,3,2-Diazaphosphole Complex, J. Chem. Soc., Chem. Commun. 1997, 2317-2318.
  28. R. Streubel, A. Ostrowski, H. Wilkens, S. Priemer, U. Rohde, Advances in 2H-azaphosphirene Complex Chemistry,Phosphorus Sulfur Relat. Elem. 1997, 124/125, 93-102.
  29. U. Rohde, H. Wilkens, R. Streubel, Synthesis of 1H-diphosphirene, Phosphorus-Carbon Cage and 2,3-Dihydro-1,2,3-tri- phosphete Complexes, Phosphorus Sulfur Relat. Elem. 1997, 124/125, 545-548.
  30. H. Wilkens, R. Streubel, First Synthesis and Structures of 2H-1,3,2-Diazaphosphole Tungsten Complexes, Phosphorus Sulfur Relat. Elem. 1997, 124/125, 83-92.
  31. Streubel, A. Ostrowski, S. Priemer, U. Rohde, J. Jeske, P. G. Jones, Syntheses and spectroscopic data of para-substituted (3-phenyl-2H-azaphosphirene) tungsten complexes, Eur. J. Inorg. Chem. 1998, 257-261.
  32. R. Streubel, Aufsehen um transiente und persistente Radikale des Phosphors?, Chem. i. u. Z. 1998, 32, 165 ("Highlight zu einem Science-Beitrag").
  33. Streubel, F. Ruthe, P. G. Jones, Syntheses of Phenyl-substituted 2H-Azaphosphirene Chromium and Molybdenum Complexes - First Evidence for Reaction Intermediates, Eur. J. Inorg. Chem. 1998, 571-574.
  34. R. Streubel, S. Priemer, F. Ruthe, P. G. Jones, D. Gudat, Syntheses of Heteroaryl-substituted 2H-Azaphosphirene Tungsten Complexes Eur. J. Inorg. Chem. 1998, 575-578.
  35. H. Wilkens, F. Ruthe, P. G. Jones, R. Streubel, Syntheses of 2H-1,3,2-Diazaphosphole, 2H-1,4,2-Diazaphosphole and 3-1,3,2-Ox-azaphospholene Complexes - First Examples of 2H-azaphosphirene Complex Formation by [2+1] Cycloaddition Reaction, Chem. Eur. J. 1998, 4, 1542-1553.
  36. H. Wilkens, F. Ruthe, P. G. Jones, R. Streubel, Transylidation of a Transiently Formed Nitrilium Phosphane Ylide Complex, J. Chem. Soc., Chem. Commun. 1998, 1529-1530.
  37. R. Streubel, H. Wilkens, F. Ruthe, P. G. Jones, Competitive formation of h1-1-phosphaallene and 1H-phosphirene complexes,J. Chem. Soc., Chem. Commun. 1998, 1761-1762.
  38. R. Streubel, U. Rohde, J. Jeske, F. Ruthe, P. G. Jones, Phosphorus-bridged Dinuclear Tungsten Amino(aryl)carbene Complexes - New Pre- cursors for 2H-azaphosphirene Tungsten Complexes bearing a s-P-bonded Cp* Group, Eur. J. Inorg. Chem. 1998, 2005-2012.
  39. R. Streubel, H. Wilkens, F. Ruthe, P. G. Jones, Bifunktionalisierte 1H-Phosphiren- und h1-1-Phosphaallen-Komplexe, Z. Anorg. Allg. Chem. 1999, 625, 102-106.
  40. U. Rohde, F. Ruthe, P. G. Jones, R. Streubel, Bildung und Struktur des ersten 7-Aza-1-phosphanorbornadien-Komplexes, Angew. Chem. 1999, 111, 158-160; Angew. Chem. Int. Ed. 1999, 38, 215-217.
  41. R. Streubel, H. Wilkens, Generation and Reactions of Transient Nitrilium Phosphane-Ylide Complexes, Phosphorus Sulfur Relat. Elem. 1999, 144-146, 473-476.
  42. H. Wilkens, R. Streubel, First Example for Competitive Formation of 1H-phosphirene and h1-1-phospha-allene Complexes, Phosphorus Sulfur Relat. Elem. 1999, 147, 429.
  43. R. Streubel, C. Neumann, Dual reaction behaviour of an in-situ generated nitrilium phosphane-ylid complex towards carbon-sulfur -systems, J. Chem. Soc., Chem. Commun. 1999, 499-500.
  44. R. Streubel, H. Wilkens, U. Rohde, A. Ostrowski, J. Jeske, F. Ruthe, P. G. Jones, Syntheses, Structures and Reactions of C-Methylcarboxylate-functionalized Small- and Medium-sized P-Heterocycle Complexes, Eur. J. Inorg. Chem. 1999, 1567-1579.
  45. R. Streubel, H. Wilkens, F. Ruthe, P. G. Jones, Photochemical generated nitrilium phosphane-ylid tungsten complexes and their reactivity towards alkyne and nitrile derivatives J. Chem. Soc., Chem. Commun. 1999, 2127-2128.
  46. H. Wilkens, A. Ostrowski, J. Jeske, F. Ruthe, P. G. Jones, R. Streubel, Synthesis of 2H-1,2-Azaphosphole Complexes by [3 + 2] Cycloaddition of Nitrilium Phosphane-Ylide Complexes with Various Alkynes; Studies of C-Substituent and Metal Effects on the Reaction Course, Organometallics 1999, 18, 5627-5642.
  47. R. Streubel, H. Wilkens, F. Ruthe, P. G. Jones, Synthesis and Characterization of some 2H-1,4,2-Diazaphosphole-, 2H-1,3,2-Diazaphosphole- and 2H-1,2-Diazaphosphole-P-sulfide Derivatives, Tetrahedron 2000, 56, 21-26.
  48. R. Streubel, M. Hobbold, J. Jeske, P. G. Jones, Synthese und Struktur von {{N-[Bis(diisopropylamino)phosphanyl]amino(phenyl)-carben}dicarbonyl(5-methylcyclopentadienyl)mangan(0)} und versuchte Darstellung von {[2-Bis(trimethylsilyl)methyl-3-phenyl-2H-azaphosphiren-P]dicarbonyl(5-methylcyclopentadienyl)mangan(0)}, J. Organomet. Chem. 2000, 595, 12-20.
  49. R. Streubel, U. Schiemann, N. Hoffmann, Y. Schiemann, P. G. Jones, D. Gudat, Intra- and Intermolecular [3+2] Cycloaddition Reactions of P-Cp*-Substituted Nitrilium Phosphane-Ylide Tungsten Complexes Organometallics 2000, 19, 475-481.
  50. R. Streubel, S. Priemer, F. Ruthe, P. G. Jones, Study on the Ring Formation of 2H-Azaphosphirene Complexes Using Sterically Demanding C-2,4,6-Trialkylphenyl-Substituted Aminocarbene Tungsten Complexes - Detection of a Key Intermediate Eur. J. Inorg. Chem. 2000, 1253-1259.
  51. R. Streubel, C. Neumann, P. G. Jones, Ferrocenium salt-induced ring expansions of a 2H-azaphosphirene complex, J. Chem. Soc., Dalton Trans. 2000, 2495-2496.
  52. R. Streubel, M. Hobbold, S. Priemer, Synthesis of the First Stable Fischer-type Carbene Metal Complex with a C-O-P Structural Motive of the Carbene Ligand, J. Organomet. Chem. 2000, 613, 56-59.
  53. R. Streubel, U. Schiemann, P. G. Jones, N. H. Tran Huy, F. Mathey, New and facile entry to Nitrilium Phosphane-Ylide Complex Chemistry using 7-phosphanorbornadiene Complexes, Angew. Chem. 2000, 112, 3845-3847; Angew. Chem. Int. Ed. 2000, 39, 3686-3688.
  54. R. Streubel, H. Wilkens, P. G. Jones, Bond-selective Nitrile Insertion into the 2H-azaphosphirene Ring System as induced by Tetracyanoethylene, Chem. Eur. J. 2000, 21, 3997-4000.
  55. G. N. Cloke, P. B. Hitchcock, U. Schiemann, R. Streubel, J. F. Nixon, D. J. Wilson, Syntheses of complexes containing the novel 1,2,5-azadiphosphole and 1,2,3-aza-diphosphole ring systems: Crystal and molecular structure of [Ir(5-C5Me5)(4-ButCPNButPCBut)], J. Chem. Soc., Chem. Commun. 2000, 1659-1660.
  56. R. Streubel, H. Wilkens, F. Ruthe, P. G. Jones, Unexpected Dimerization of a 2H-Azaphosphirene Complex, J. Chem. Soc., Chem. Commun. 2000, 2453-2454.
  57. R. Streubel, S. Priemer, J. Jeske, P. G. Jones, Stereochemically Defined Metal Carbene Complexes as Chemical Probes for Studies of the Ring Formation of 2H-Azaphosphirene Complexes, J. Organomet. Chem. 2001, 617-618, 423-434.
  58. A. Ostrowski, J. Jeske, P. G. Jones, R. Streubel, Synthese und spektroskopische Charakterisierung einiger Pentacarbonylwolfram(0)-Komplexe mit mono- und bicyclischen Phosphiran-Liganden: Kristallstruktur von [{(Me3Si)2HCPC(H2)-C(H)Ph}W(CO)5], Z. Anorg. Allg. Chem. 2001, 627, 1135-1140.
  59. R. Streubel, U. Schiemann, P. G. Jones, J. Grunenberg, H.-M. Schiebel, D. Gudat, Synthesis of the first 1,3,4-Triphosphole Complex, Angew. Chem. 2001, 113, 2531-2534; Angew. Chem. Int. Ed. 2001, 40, 2471-2474.
  60. R. Streubel, U. Schiemann, N. Hoffmann, P. G. Jones: Strong evidence for stereoselective 1,3-additions of transient nitrilium phosphane-ylide complexes: Synthesis of the first 1-aza-3-phosphabuta-1,3-diene complexes, J. Chem. Soc., Chem. Commun. 2001, 1334-1335.
  61. R. Streubel, U. Schiemann, N. H. Tran Huy, F. Mathey: Reactivity of Sterically Unencumbered Transient Nitrilium Phosphanylide Complexes towards 1-Piperidinocarbonitrile: A Case Study, Eur. J. Inorg. Chem. 2001, 3175-3179. 
    R. Streubel, C. Neumann: Reactions of transiently formed nitrilium phosphanylid chromium, molybdenum and tungsten complexes with heterocumulenes, Heteroatom. Chem. 2002, 13, 72-76.
  62. C. Neumann, E. Ionescu, U. Schiemann, M. Schlenker, M. Bode, F. Ruthe, P. G. Jones, R. Streubel: Catalytic and selective ring expansion reactions of o-phenyl-substituted 2H-azaphosphirene tungsten complexes, J. Organomet. Chem. 2002, 643-644, 253-264.
  63. A. Alijah, S. Grigoleit, R. Streubel, W.W. Schoeller: Theoretical calculations on donor adducts of terminal phosphinidene complexes, J. Organomet. Chem. 2002, 643-644, 223-230.
  64. R. Streubel, N. Hoffmann, F. Ruthe, P. G. Jones: Determining Substrate Selectivity and Regiochemistry of Nitrilium Phosphanylide Tungsten Complexes in Cycloaddition Reactions with Terminal Alkynes, Polyhedron 2002, 21, 119-124.
  65. R. Streubel, H. Wilkens, C. Neumann: Catalytic Reactions in Heterophosphole Complex Chemistry, Phosphorus Sulfur Relat. Elem. 2002. 177, 1563-1565.
  66. R. Streubel, N. Hoffmann, H.-M. Schiebel, F. Ruthe, P. G. Jones: Synthesis of the first 2H-1,2-azaphosphole complexes with P,C and P,N ylide functional groups, Eur. J. Inorg. Chem. 2002, 957-967.
  67. R. Streubel: Chemistry of 3-2H-azaphosphirene Metal Complexes, Coord. Chem. Rev. 2002, 227, 175-192.
  68. N. Hoffmann, P. G. Jones, R. Streubel: Intramolekulare [3+2]-Cycloaddition eines Nitriliumphosphan-Ylid-Komplexes an die P-Phenylgruppe eines Wittig-Ylides, Angew. Chem. 2002, 114, 1226-1228; Angew. Chem. Int. Ed. 2002, 41, 1186-1188.
  69. N. Hoffmann, C. Wismach, P. G. Jones, R. Streubel, N. H. Tran Huy, F. Mathey: Synthesis of the first 1,2,3,4-azatriphospholene complex J. Chem. Soc., Chem. Commun. 2002, 454-455.
  70. R. Streubel: Transient Nitrilium Phosphanylid Complexes – New Versatile Building Blocks in Phosphorus Chemistry, Top. Curr. Chem. 2002, 223, 91-109.
  71. E. Ionescu, P. G. Jones, R. Streubel: Synthesis of the first 2,3-dihydro-1,2,3-azadiphosphete complex, J. Chem. Soc., Chem. Commun. 2002, 2204-2205.
  72. A. A. Khan, C. Wismach, P. G. Jones, R. Streubel, Report on a very unconventional access to [(Me3Si)2HCPCl2W(CO)5] and its reaction to various structurally characterized organo chalcogenophosphonic derivatives, J. Chem. Soc., Dalton Trans. 2003, 2483 - 2487.
  73. R. Streubel, N. Hoffmann, G. von Frantzius, C. Wismach, P. G. Jones, H.-M. Schiebel, J. Grunenberg, H. Vong, P. Chaigne, C. Compain, N. H. Tran Huy, F. Mathey: Multifunctional 2H-1,2-azaphosphole complexes – A good starting point for the synthesis of functional 1,2-azaphospholide complexes? Organometallics 2003, 22, 5427-5435.
  74. N. Hoffmann, C. Wismach, L. Ernst, H.-M. Schiebel, P. G. Jones, R. Streubel: A new concept for the efficient synthesis of chiral phosphorus-nitrogen-carbon cage compounds, Eur. J. Inorg. Chem. 2003, 1815-1821.
  75. J. Grunenberg, R. Streubel, G. von Frantzius, W. Marten: The strongest bond in the universe? Accurate calculation of compliance matrices for the ions N2H+, HCO+ and HOC+, J. Chem. Phys. 2003, 119, 165-169.
  76. C. Neumann, A. Prehn Junquera, C. Wismach, P. G. Jones, R. Streubel: Synthesis of functional 3-1,3,5-oxazaphospholene and 2H-1,4,2-diazaphosphole complexes via catalytic ring expansion reactions of a 2H-azaphosphirene complex, Tetrahedron 2003, 59, 6213-6220.
  77. A. A. Khan, C. Neumann, C. Wismach, P. G. Jones, R. Streubel: Synthesis of a C-pyridine-substituted 2H-1,3,2-diazaphosphole complex and subsequent oxidation to its P(V)-sulfide and P(V)-selenide derivatives J. Organomet. Chem. 2003, 682, 212-217.
  78. A. A. Khan, C. Wismach, P. G. Jones, R. Streubel: Electrophilic terminal phosphinidene complex-Lewis base adducts: Chemistry between carbon-halide bond activation and weak Lewis base adduct formation J. Chem. Soc., Chem. Commun. 2003, 2892-2893.
  79. A. A. Khan, C. Wismach, P. G. Jones, R. Streubel: Synthesis of 2,4,6- Tris-piperidino-1,3,5-triazine from Metal Carbonyls M(CO)6 (M = Cr, Mo, W) Catalyzed Cyclotrimerization of Piperidinonitrile and its Crystal Structure, Acta Cryst. 2003, E59, 1757-1758.
  80. N. Hoffmann, R. Streubel, L. Ricard, N. Hoa Tran Huy, F. Mathey: Cycloaddition reaction of parent ketene with 1,3-dipolar adducts of [RP-W(CO)5] and electron-rich nitriles, C. R. Chimie 2004, 7, 927-930.
  81. R. Streubel, E. Ionescu, N. Hoffmann: Syntheses, structures and reactions of new and novel four-, five- and six-membered unsaturated phosphorus N,P-heterocycle complexes Phosphorus Sulfur Relat. Elem. 2004, 809-811.
  82. R. Streubel, M. Bode, U. Schiemann, C. Wismach, P. G. Jones, A. Monsees: Synthesis of the first Pentacarbonyltungsten(0) Complexes with P-Pentamethyl-cyclopentadienyl-substituted 1H-Phosphirene Ligands: Crystal Structure of [{(Me5C5PC(H)=CPh}W(CO)5] Z. Anorg. Allg. Chem. 2004, 630, 1215-1219.
  83. R. Streubel: 15-Phosphinines, Science of Synthesis 2005,Vol.15, 1157-1179.
    E. Ionescu, H. Wilkens, R. Streubel: Strong evidence for an unconventional 1,2-(C->P)-silyl migration: formation and reactions of a P-silyl phosphaalkene complex Organosilicon Chemistry VI - From Molecules to Materials, Ed. N. Auner, Wiley, 2005, 202-208.
  84. E. Ionescu, G. von Frantzius, P. G. Jones, R. Streubel: Photochemical and thermal reactions of a 2H-azaphosphirene complex with isonitriles, Organometallics 2005, 24, 2237-2240.
  85. G. von Frantzius, J. Grunenberg, R. Streubel: Strong evidence for an unconventional 1,2-(C->P)-silyl migration: DFT structures and bond strengths (compliance constants) Organosilicon Chemistry VI - From Molecules to Materials, Ed. N. Auner, Wiley, 2005, 209-215.
  86. G. Becker, H. Brombach, S. T. Horner, E. Niecke, W. Schwarz, R. Streubel, E.-U. Würthwein: Synthesis and Structure of K+[iPrN=C=P]–, a 1-Aza-33-phospha-3-allenide Inorg. Chem. 2005, 44, 3080-3086.
  87. E. Ionescu, B. Gehrhus, P. B. Hitchcock, M. Nieger, R. Streubel: Surprising reactions of a 2H-azaphosphirene complex with a silylene J. Chem. Soc., Chem. Commun. 2005, 4842-4844.
  88. G. von Frantzius, R. Streubel, K. Brandhorst, J. Grunenberg: How strong is an agostic bond? Direct assessment of agostic interactions using the generalized compliance matrix. Organometallics 2006, 25, 118-121.
  89. R. Streubel, H. Wilkens, F. Ruthe, P. G. Jones: 1,2-Azaphospholene complexes through metal-directed synthesis Organometallics 2006, 25, 4830-4834.
  90. Z. Benko, R. Streubel, L. Nyulaszi: Stability of phosphinidenes – Are they synthetically accessible? J. Chem. Soc., Dalton Trans. 2006, 36, 4321-4327.
  91. R. Streubel: Crosslinking in molecular main group element chemistry, Angew. Chem. 2006, 118, 6568-6569; Angew. Chem. Int. Ed. 2006, 45, 6418-6419.
  92. R. Streubel, G. von Frantzius: Rearrangement of Molecular Complexes, NICS Proceedings, Jülich, 2006.
  93. M. Bode, M. Nieger, R. Streubel: Synthesis of the first 1,3,43-dioxaphospholane complexes Organometallics 2007, 26, 245-246.
  94. A. Özbolat, A. A. Khan, G. von Frantzius, M. Nieger, R. Streubel: Dehydroiodination of iodo- and diiodomethane by a transient phosphinidene complex, Angew. Chem. 2007, 119, 2150-2154; Angew. Chem. Int. Ed. 2007, 46, 2104-2107.
  95. R. Streubel, M. Bode, G. von Frantzius, C. Hrib, P. G. Jones, A. Monsees: Metal-directed synthesis of complexes featuring functional P,C-cage ligands with P-P bonds, Organometallics 2007, 26, 1371-1375.
  96. A. Özbolat, E. Ionescu, G. von Frantzius, S. Sauerbrey, M. Nieger, P. G. Jones, R. Streubel: Attempted synthesis of 1-aza-33-phospha-1-allenide complexes: Structure and reactions of an unusual phosphanide complex Organometallics 2007, 26, 4021-4024.
  97. A. Özbolat, G. von Frantzius, J. Marinas Pérez, M. Nieger, R. Streubel, Strong evidence for a transient phosphinidenoid complex Angew. Chem. 2007, 119, 9488-9491; Angew. Chem. Int. Ed. 2007, 46, 9327-9330.
  98. H. Helten, C. Neumann, A. Espinosa, P. G. Jones, M. Nieger, R. Streubel, Evidence for ligand-centered reactivity of a 17e radical cationic 2H-azaphosphirene complex Eur. J. Inorg. Chem. 2007, 4669-4678.
  99. M. Bode, G. Schnakenburg, P. G. Jones, R. Streubel, Synthesis novel O,P,C cage complexes via thermal C-O ring-opening of a oxaphos-phirane complex Organometallics 2008, 27, 2664-2667.
  100. A. Özbolat, G. von Frantzius, W. Hoffbauer, R. Streubel, Isolation of the first Li/halogen phosphinidenoid transition-metal complex J. Chem. Soc., Dalton Trans. 2008, 20, 2674-2676.
  101. O. Krahe, F. Neese, R. Streubel, The quest for ring-opening of oxaphosphirane complexes: a coupled cluster and density functional study of CH3PO isomers and their Cr(CO)5 complexes Chem. Eur. J. 2009, 15, 2594-2461.
  102. H. Helten, J. M. Pérez, G. Schnakenburg, R. Streubel: First ring-expansion reactions of a transition-metal coordinated 33-oxaphos-phirane Organometallics 2009, 28, 1221-1226.
  103. H. Helten, M. Engeser, D. Gudat, R. Schilling, G. Schnakenburg, M. Nieger, R. Streubel: Protonation of 2H-azaphosphirene complexes: P-N bond activation and ring expansion reactions Chem. Eur. J. 2009, 15, 2602-2616.
  104. R. Streubel, M. Bode, J. M. Pérez, G. Schnakenburg, J. Daniels, P. G. Jones, Facile synthesis of pentacarbonyltungsten(0) complexes with oxaphosphirane ligands, Z. Anorg. Allg. Chem. 2009, 635, 1163-1171.
  105. H. Helten, G. von Frantzius, G. Schnakenburg, J. Daniels, R. Streubel, How To Tune Acid-Induced Ring Enlargement Reactions - The Strange Case of 2H-Azaphosphirene Complexes and Its Surprising Dichotomy Eur. J. Inorg. Chem. 2009, 2062-2065.
  106. R. Streubel, M. Beckmann, C. Neumann, S. Fankel, H. Helten, O. Feier-Iova, P.G. Jones, M. Nieger, Synthesis, structure and ring expansion reactions of a C-ferrocenyl-substituted 2H-azaphosphirene tungsten complex Eur. J. Inorg. Chem. 2009, 2090-2095.
  107. H. Helten, S. Fankel, O. Feier-Iova, M. Nieger, A. Espinosa, R. Streubel, Strong Evidence for an Unprecedented Borderline Case of Dissociation and Cycloaddition in Open-Shell 1,3-Dipole Chemistry: Transient Nitrilium Phosphane-Ylide Complex Radical Cations Eur. J. Inorg. Chem. 2009, 3226-3237.
  108. M. Bode, J. Daniels, R. Streubel, Surprising formation of a novel P,C-cage ligand via a P-C5Me5 substituted Li/Cl phosphinidenoid complex Organometallics 2009, 28, 4636-4638.
  109. R. Streubel, A. Özbolat-Schön, M. Bode, Jörg Daniels, Gregor Schnakenburg, Francesc Teixidor, Clara Vinas, Albert Vaca, Ariadna Pepiol, Pau Farràs, Investigations on the reactivity of Li/Cl phosphinidenoid tungsten complexes towards various iodine compounds Organometallics 2009, 28, 6031-6035.
  110. G. von Frantzius, R. Streubel, Calculation of 31P and 183W NMR Chemical Shifts and Nuclear Spin-Spin Coupling Constants in Phosphinidenoid and other Transition Metal Complexes by the ZORA DFT Method, NICS Proceedings, Jülich, 2009.
  111. M. Bode, G. Schnakenburg, J. Daniels, A. Marinetti, R. Streubel, Partial ring-opening and ligand rearrangement reactions of P,C-cages to yield unusual phosphinous acids stabilized by pentacarbonyltungsten, Organometallics 2010, 29, 656-661.
  112. J. M. Pérez, H. Helten, B. Donnadieu, C. Reed, R. Streubel, Protonation-Induced Rearrangement of an Oxaphosphirane Complex, Angew. Chem. 2010, 122, 2670-2674; Angew. Chem. Int. Ed. 2010, 49, 2615-2618.
  113. S. Fankel, H. Helten, G. von Frantzius, G. Schnakenburg, J. Daniels, V. Chu, C. Müller, R. Streubel, Novel access to azaphosphiridine complexes and first applications using broensted acid-induced ring expansion reactions, Dalton Trans. 2010, 39, 3472-3481.
  114. H. Helten, M. Beckmann, G. Schnakenburg, R. Streubel, Synthesis and Reactivity of an Unusual Ferrocenophane Biscarbene Complex Eur. J. Inorg. Chem. 2010, 16, 2337-2341.
  115. H. Helten, J. Daniels, M. Nieger, R. Streubel, Extended  conjugation in 2H-1,4,2-diazaphosphole complexes, New. J. Chem. 2010, 34, 1593-1602.
  116. A. Özbolat-Schön, M. Bode, G. Schnakenburg, A. Anoop, M. van Gastel, F. Neese, R. Streubel, First insights into the chemistry of transient P-Cl functional phosphanyl complexes, Angew. Chem. 2010, 122, 7047-7051; Angew. Chem. Int. Ed. 2010, 49, 6894-6898.
  117. J. M. Pérez, C. Albrecht, H. Helten, G. Schnakenburg, R. Streubel, Competing ring cleavage of transient O-protonated oxaphosphirane complexes: 1,3-oxaphospholane and 2 Wittig ylide complex formation, Chem. Commun. 2010, 46, 7244-7246.
  118. R. Streubel, H. Helten, J. M. Pérez, J. Daniels, M. Nieger, Developing click reactions of a 3-ferrocenyl-2H-azaphosphirene complex, Dalton Trans. 2010, 39, 11445-11450.
  119. V. Nesterov, L. Duan, G. Schnakenburg, R. Streubel, New Access to and Reactions of P-Functional Acylphosphane Complexes Eur. J. Inorg. Chem. 2011, 567-572.
  120. S. Sauerbrey, P. K. Majhi, J. Daniels, G. Schnakenburg, G. M. Brändle, K. Scherer, R. Streubel, Synthesis, structure and reactions of 1-tert-butyl-2-(diphenylphosphino)imidazole, Inorg. Chem. 2011, 50, 793-799.
  121. R. Streubel, S. Sauerbrey, M. Nieger, Synthesis and structure of {{amino(triorganosilyl)carbene}pentacarbonyl-tungsten(0)} complexes and attempted synthesis of {[2-bis(trimethylsilyl)methyl-3-triorganosilyl-2H-azaphosphirene-κP]pentacarbonyltungsten(0)} J. Organomet. Chem. 2011, 696, 2035-2039.
  122. H. Helten, G. Schnakenburg, A. J. Arduengo III, R. Streubel, When Sterics Overcome Electronics: An Unusual Haptotropic P→N Penta-carbonyltungsten Shift, Organometallics 2011, 30, 84-91.
  123. C. Schulten, G. von Frantzius, G. Schnakenburg, R. Streubel, Deoxygenation of Isocyanates via Transient Electrophilic Terminal Phosphinidene Complexes – are Strained P-Heterocycles Involved? Heteroat. Chem. 2011, 22, 275-286.
  124. A. Espinosa, R. Streubel, Computational studies on azaphosphiridines or how to effect ring-opening processes via selective bond activation, Chem. Eur. J. 2011, 17, 3166-3178.
  125. J. M. Pérez, H. Helten, G. Schnakenburg, R. Streubel, An Approach to 1,3,4-Dioxaphospholane Complexes: Acid-Induced Ring Expansion of an Oxaphosphirane Complex. The Problem of Construction and Deconstruction of O,P-Heterocycles, Chem. Asian J. 2011, 6, 1539-1545.
  126. H. Helten, G. Schnakenburg, R. Streubel, Click reactions of 2H-azaphosphirene chromium and molybdenum complexes and a surprisingly facile access to a 2H-1,4,2-diazaphosphole derivative, Polyhedron 2011, 30, 1799-1805.
  127. C. Albrecht, M. Bode, J. M. Pérez, G. Schnakenburg, R. Streubel, First examples of oxaphosphirane chromium and molybdenum complexes: syntheses, structures and reactions, Dalton Trans. 2011, 40, 2654-2665.
  128. L. Duan, G. Schnakenburg, R. Streubel, Generation and decomposition of Li/OR phosphinidenoid complexes, Organometallics 2011, 30, 3246-3249.
  129. J. M. Pérez, M. Klein, A. Kyri, G. Schnakenburg, R. Streubel, First examples of spirooxaphosphirane complexes, Organometallics 2011, 30, 5636-5640.
  130. L. Duan, V. Nesterov, J. Runyon, G. Schnakenburg, A. J. Arduengo III, R. Streubel, Synthesis of stabilized phosphinidenoid complexes using weakly coordinating cations Austr. J. Chem. 2011, 64, 1583-1586.
  131. L. Duan, G. Schnakenburg, R. Streubel, Synthesis of aminophosphane complexes: Searching the boundary between phosphanide and phosphinidenoid complex chemistry Eur. J. Inorg. Chem. 2012, 2314-2319; DOI: 10.1002/ejic.201101437
  132. V. Nesterov, A. Özbolat-Schön, G. Schnakenburg, L. Shi, A. Cangönül, M. van Gastel, F. Neese, R. Streubel, An Unusal Case of Facile Non-Degenerate P-C Bond Making and Breaking Chem. Asian J. 2012, 7, 845-854; DOI: 10.1002/asia.201200161
  133. S. Sauerbrey, P. K. Majhi, G. Schnakenburg, A. J. Arduengo III, R. Streubel, Synthesis, structure and reactivity of 4-phosphanylated 1,3-dialkyl-imidazole-2-thiones Dalton Trans. 2012, 41, 5368-5376; DOI: 10.1039/C2DT12483A
  134. A. Espinosa, C. Goméz, R. Streubel, Single Electron Transfer-Mediated Selective endo- and exocyclic Bond Cleavage Processes in Azaphosphiridine Chromium(0) Complexes: A Computational Study Inorg. Chem. 2012, 51, 7250-7256; DOI: 10.1021/ic300522g
  135. L. Duan, G. Schnakenburg, J. Daniels, R. Streubel, P-OR functional phosphanido and/or Li/OR phosphinidenoid complexes? Eur. J. Inorg. Chem. 2012, 3490-3499; DOI: 10.1002/ejic.201200368
  136. R. Streubel, J. M. Villaba Franco, G. Schnakenburg, A. Espinosa Ferao, Reactivity of terminal phosphinidene versus Li/Cl phosphinidenoid complex in cycloaddition chemistry Chem. Commun. 2012, 48, 5986-5988; DOI: 10.1039/c2cc31851b
  137. R. Streubel, E. Schneider, G. Schnakenburg, Novel spirooxaphosphirane complexes Organometallics 2012, 31, 4707-4710; DOI: 10.1021/om300152y
  138. V. Nesterov, S. Schwieger, G. Schnakenburg, S. Grimme, R. Streubel, SET-oxidation of Li/X phosphinidenoid complexes by TEMPO Organometallics 2012, 31, 3457-3459; DOI: 10.1021/om300099g
  139. C. Albrecht, L. Shi, J. M. Pérez, M. van Gastel, S. Schwieger, F. Neese, R. Streubel, Deoxygenation of coordinated oxaphosphiranes – A novel route to P-C double bond systems Chem. Eur. J. 2012, 18, 9780-9783; DOI: 10.1002/chem.201201405
  140. R. Streubel, M. Klein, G. Schnakenburg, Probing the group tolerance of a Li/Cl phosphinidenoid complex using alkenyl substituted aldehydes Organometallics 2012, 31, 4711-4715; DOI: 10.1021/om300177c
  141. S. Sauerbrey, P. K. Majhi, G. Schnakenburg, A. J. Arduengo III, R. Streubel, Synthesis of bis(imidazole-2-thione-4-yl)phosphanes Heteroatom. Chem. 2012, 23, 513-519; DOI: 10.1002/hc.21043
  142.  A. Espinosa, R. Streubel, Exocyclic bond cleavage in oxaphosphirane complexes? Chem. Eur. J. 2012, 18, 13405-13411; DOI: 10.1002/chem.201201057
  143. P. K. Majhi, S. Sauerbrey, G. Schnakenburg, A. J. Arduengo III, R. Streubel, Synthesis of backbone P-functionalized imidazol-2-ylidene complexes – en route to novel functional ionic liquids, Inorg. Chem. 2012, 51, 10408-10416; DOI: 10.1021/ic301641z
  144. V. Nesterov, G. Schnakenburg, A. Espinosa, R. Streubel, Synthesis and reactions of a room temperature stable Li/Cl phosphinidenoid complex, Inorg. Chem. 2012, 51, 12343-12349; DOI: 10.1021/ic301652u
  145. C. Schulten, G. von Frantzius, A. Espinosa Ferao, G. Schnakenburg, R. Streubel, Deoxygenation of carbon dioxide by electrophilic terminal phosphinidene complexes, Chem. Sci. 2012, 3, 3526-3533; DOI: 10.1039/c2sc21081a
  146. M. Yoshifuji, H. Hirano, G. Schnakenburg, R. Streubel, E. Niecke, S. Ito, New aspects of 1,3-diphosphacyclobutane-2,4-diyls, Helv. Chim. Acta 2012, 95, 1723-1729; DOI: 10.1002/hlca.201200442
  147. R. Streubel, A. Özbolat-Schön, G. von Frantzius, H. Lee, J. Daniels, G. Schnakenburg, D. Gudat, Li/X phosphinidenoid complexes of group 6 transition metal carbonyls – A combined experimental and theoretical study on structures and spectroscopic properties, Inorg. Chem. 2013, 52, 3313-3325; DOI: 10.1021/ic302786v
  148. V. Nesterov, T. Heurich, R. Streubel, First synthesis of chloroformylphosphane complexes, Pure Appl. Chem. 2013, 85, 829-834; DOI: 10.1351/PAC-CON-12-07-14
  149. C. Albrecht, E. A. Schneider, M. Engeser, G. Schnakenburg, A. Espinosa, R. Streubel, Synthesis and DFT Calculations of Spirooxaphosphirane Complexes Dalton Trans. 2013, 42, 8897-8906; DOI: 10.1039/C3DT50556A
  150. L. Abdrakhmanova, A. Espinosa Ferao, R. Streubel, Reaction of Li/Cl phosphinidenoid complexes with a phosphite substituted ketone: access to complexes with a novel mixed-valence polycyclic P,C-ligand system Dalton Trans. 2013, 42, 10510-10514; DOI: 10.1039/c3dt50902h
  151. P. K. Majhi, S. Sauerbrey, A. Leiendecker, G. Schnakenburg, A. J. Arduengo III, R. Streubel, Synthesis and first complexes of P(V/III) and P(V/V)-bifunctional imidazole-2-thiones, Dalton Trans. 2013, 42, 13126-13136; DOI: 10.1039/C3DT51557E
  152. P. K. Majhi, G. Schnakenburg, Z. Kelemen, L. Nyulaszi, D. P. Gates, R. Streubel, Synthesis of a novel imidazolium phosphanide zwitterion and its conversion into anionic imidazol-2-ylidene derivatives, Angew. Chem. 2013, 125, 10264-10267; Angew. Chem. Int. Ed. 2013, 52, 10080-10083; DOI: 10.1002/ange.201304431
  153. J. M. Villalba Franco, A. Espinosa, G. Schnakenburg, R. Streubel, The azaphosphiridine complex/terminal phosphinidene complex rearrangement: a case study on non-covalent interactions of reactive species, Chem. Commun. 2013, 49, 9648-9650; DOI: 10.1039/C3CC45477K
  154. G. von Frantzius, A. Espinosa, R. Streubel, Coordination of CO to low-valent phosphorus centres and other related P-C bonding situations. A theoretical case study, Chem. Sci. 2013, 4, 4309-4322; DOI: 10.1039/C3SC52027G
  155. M. Klein, C. Albrecht, G. Schnakenburg, R. Streubel, A new route to phosphaalkene chelate complexes: SET deoxygenation of oxaphos-phirane complexes followed by intramolecular CO substitution, Organometallics 2013, 32, 4938-4943; DOI: 10.1021/om400654c
  156. L. Abdrakhmanova, G. Schnakenburg, A. Espinosa Ferao, R. Streubel, The 3-acetyl-oxaphosphirane/1,3,2-dioxaphosphol-4-ene rearrangement, Eur. J. Inorg. Chem. 2014, 1727-1734; DOI: 10.1002/ejic.201301169
  157. E. B. Garner III, A. J. Arduengo III, R. Streubel, D. Dixon, Electronic Structure Predictions of the Properties of Non-innocent Ligands in Group 6B Transition Metal Complexes, Dalton Trans. 2014, 43, 2069-2078; DOI: 10.1039/C3DT52056K
  158. R. Streubel, A. Kyri, G. Schnakenburg, Synthesis of Li/OR phosphinidenoid complexes: on the evidence for intramolecular O-Li donation and the effect of cation encapsulation, Dalton Trans. 2014, 43, 2088-2097; DOI: 10.1039/C3DT52269E
  159. V. Nesterov, A. Espinosa, G. Schnakenburg, R. Streubel, Novel N,P,C-cage complex via rearrangement of a tricyclic phosphirane complex. On the importance of non-covalent interactions, Chem. Eur. J. 2014, 20, 7010-7016; DOI: 10.1002/chem.201305061
  160. D. Escudéro, A. Frontera, R. Streubel, Electronic Structure of N2P2 Four-Membered Rings, Chem. Phys. Chem. 2014, 1599-1603; DOI: 10.1002/cphc.201301233
  161. A. Bauzá, R. Streubel, A. Frontera, On the Relationship between Ring Strain Energies and “atoms-in-molecules” Properties in N2P2 Rings, Chem. Phys. Lett. 2014, 597, 40-44; DOI: 10.1016/j.cplett.2014.02.018
  162. A. Espinosa, E. de las Heras, R. Streubel, Oxaphosphirane-borane complexes: Ring strain and migratory insertion reactions, Inorg. Chem. 2014, 53, 6132–6140; DOI: 10.1021/ic500536h
  163. A. Espinosa, L. Abdrakhmanova, R. Streubel, Theoretical study on novel mixed-valence, P-H-functional P-ligands and their tautomerization, Heterat. Chem. 2014, 25, 651-657; DOI: 10.1002/hc.21207
  164. P. K. Majhi, G. Schnakenburg, S. C. Serin, D. P. Gates, R. Streubel, Mono- and hetero-dinuclear complexes of Janus-head NHC ligands possessing backbone phosphinoyl groups: the case of soft and hard metal centers, Eur. J. Inorg. Chem. 2014, 4975-4983; DOI:10.1002/ejic.201402440
  165. A. Kyri, G. Schnakenburg, R. Streubel, Synthesis and Reactions of the First 1,2-Oxaphosphetane complexes, Angew. Chem. 2014, 126, 10985 –10988; Angew. Chem. Int. Ed. 2014, 53, 10809 –10812; DOI: 10.1002/anie.201404877
  166. V. Nesterov, Z.-W. Qu, G. Schnakenburg, S. Grimme, R. Streubel, Selective phosphanyl complex trapping using TEMPO: synthesis of the first P-nitroxyl substituted phosphane complex, Chem. Commun. 2014, 50, 12508-12511; DOI: 10.1039/C4CC06084A
  167. P. K. Majhi, G. Schnakenburg, R. Streubel, From bis(imidazole-2-thion-4-yl)phosphane to a flexible P-bridged bis(NHC) ligand and its silver complex, Dalton Trans. 2014, 43, 16673-16679; DOI: 10.1039/c4dt02479f
  168. J. M. Villalba Franco, G. Schnakenburg, A. Espinosa Ferao, R. Streubel, Unprecedented ring-ring interconversion of N,P,C-cage ligands, Chem. Eur. J. 2015, 21, 3727-3735; DOI: 10.1002/chem.201405754
  169. A. Bauzá, D. Escudéro, A. Frontera, R. Streubel, Electronic structure of N2P2 four-membered rings and the effect of their ligand coordination to M(CO)5 (Cr, Mo and W), Organometallics 2015, 34, 355-360; DOI: 10.1021/om501142k
  170. T. Sasamori, T. Sugahara, T. Agou, J.-D. Guo, S. Nagase, R. Streubel, N. Tokitoh, Synthesis and Characterization of a 1,2-Digermabenzene, Organometallics 2015, 34, 2106-2109; DOI: 10.1021/om501204u
  171. P. K. Majhi, G. Schnakenburg, A. J. Arduengo III, R. Streubel, Synthesis and oxidative desulfurization of P(V)-functionalized imidazole-2-thiones: Easy access to P-functional ionic liquids, Austr. J. Chem. 2015, 68, 1282-1292; DOI: 10.1071/CH14726
  172. J. M. Villalba Franco, T. Sasamori, G. Schnakenburg, A. Espinosa Ferao, R. Streubel, Going for strain: synthesis of the first 3-imino-azaphosphiridine complexes and their surprising conversion into oxaphosphirane complex valence isomers, Chem. Commun. 2015, 51, 3878-3881; DOI: 10.1039/C4CC10266E
  173. R. Streubel, C. Murcia-Garcia, G. Schnakenburg, A. Espinosa, Transient terminal phosphinidene oxide complexes – key intermediates in the formation of O,P,C-cages from oxaphosphirane complexes, Organometallics 2015, 34, 2676-2682; DOI: 10.1021/acs.organomet.5b00029
  174. C. Murcia, G. Schnakenburg, A. Bauzá, A. Frontera, R. Streubel, Surprising behaviour of M–CO(lone pair)•••π(arene) interactions in the solid state of fluorinated oxaphosphirane complexes CrystEngComm. 2015, 17, 1769-1772; DOI: 10.1039/C5CE01331C
  175. C. Murcia, G. Schnakenburg, A. Bauzá, A. Frontera, R. Streubel, On the nature of M-CO(lone pair)···π(arene) interactions in the solid state of fluorinated oxaphosphirane complexes CrystEngComm. 2015, 17, 6736-6743; DOI: 10.1039/C5CE01331C
  176. Z. Kelemen, R. Streubel, L. Nyulaszi, Zwitterionic Carbene adducts and their Carbene Isomers, RSC Adv. 2015, 5, 41795–41802; DOI: 10.1039/C5RA07039B
  177. R. Streubel, J. Faßbender, G. Schnakenburg, A. Espinosa, Formation of transient and stable 1,3-dipole complexes with P,S,C and S,P,C ligand skeletons Organometallics 2015, 34, 3103-3106; DOI: 10.1021/acs.organomet.5b00386
  178. J. M. Villalba Franco, Takahiro Sasamori, G. Schnakenburg, A. Espinosa Ferao, R. Streubel, Substrate stimuli-responsive FLP-type reactivity – first insights Chem. Eur. J. 2015, 21, 9650-9655; DOI: 10.1002/chem.201501628
  179. T. Sasamori, J. M. Villalba Franco, J.-D. Guo, K. Sugamata, S. Nagase, R. Streubel, N. Tokitoh, Selenium-Substituted Phosphaalkenes Obtained through 1,2- Elimination of Chlorosilanes from Selenenylchlorophosphines Eur. J. Inorg. Chem. 2016, 678-684; DOI: 10.1002/ejic.201500989
  180. M. Klein, G. Schnakenburg, A. Espinosa Ferao, N. Tokitoh, R. Streubel, Reactions of Li/Cl Phosphinidenoid Complexes with 1,3,4,5- Tetramethylimidazol-2-ylidene: A New Route to N-Heterocyclic Carbene Adducts of Terminal Phosphinidene Complexes and an Unprecedented Transformation of an Oxaphosphirane Complex Eur. J. Inorg. Chem. 2016, 685–690, DOI: 10.1002/ejic.201500959
  181. M. Klein, G. Schnakenburg, A. Espinosa Ferao, R. Streubel, Rearrangement and deoxygenation of 3,3’-bis(2-pyridyl)oxaphosphirane complexes Dalton Trans. 2016, 45, 2085-2094; DOI: 10.1039/C5DT03404C
  182. I. Begum, G. Schnakenburg, R. Streubel, Synthesis and reactions of C-phosphanylated thiazole-2-thiones Dalton Trans. 2016, 45, 2955-2962, DOI: 10.1039/c5dt03662c
  183. C. Murcia Garcia, A. Espinosa Ferao, G. Schnakenburg, R. Streubel, CPh3 as a functional group in P-heterocyclic chemistry: elimination of HCPh3 in the reaction of P-CPh3 substituted Li/Cl phosphinidenoid complexes with Ph2C=O Dalton Trans. 2016, 45, 2378-2385. DOI: 10.1039/c5dt04595a
  184. P. K. Majhi, Keith C. F. Chow, T. H. H. Hsieh, E. G. Bowes, G. Schnakenburg, P. Kennepohl, R. Streubel, D. P. Gates, Even the normal is abnormal: N-heterocyclic carbene C2 binding to a phospha-alkene without breaking the P=C -bond Chem. Commun. 2016, 52, 998-1001, DOI: 10.1039/c5cc08181e
  185. T. Heurich, S. Nožinović, G. Schnakenburg, H. Matsuoka, O. Schiemann, Z.-W. Qu, S. Grimme, R. Streubel, Synthesis and rearrangement of P-nitroxyl substituted P(III) and P(V) phosphanes – a combined experimental and theoretical case study Chem. Eur. J. 2016, 22, 10102-10110. DOI: 10.1002/chem.201504900
  186. A. W. Kyri, G. Schnakenburg, R. Streubel, C-Trifluoromethyl substituted 1,2-oxaphosphetane complexes: A synthetic and structural study Organometallics 2016, 35, 563–568, DOI: 10.1021/acs.organomet.5b00974
  187. J. M. Villalba Franco, G. Schnakenburg, A. Espinosa Ferao, R. Streubel, Coordination chemistry of a low-coordinate non-metal element: the case of electrophilic terminal phosphinidene complexes, Dalton Trans. 2016, 45, 13951-13956. DOI: 10.1039/c6dt02909d
  188. P. K. Majhi, A. W. Kyri, A. Schmer, G. Schnakenburg, R. Streubel, Synthesis and deprotonation of aminophosphane complexes: Potassium phosphini-denoid complexes and a new synthetic protocol for complexes with three-membered P-ring ligands Chem. Eur. J. 2016, 22, 15413-15419. DOI: 10.1002/chem.201600850
  189. P. K. Majhi, G. Schnakenburg, A. J. Arduengo III, R. Streubel, Backbone phosphonamide functionalized imidazol-2-ylidene complexes Austr. J. Chem. 2016, 69, 1186-1192. DOI: org/10.1071/CH16132
  190. P. K. Majhi, A. Koner, Z. Kelemen, G. Schnakenburg, L. Nyulaszi, R. Streubel, Applying imidazole-2-thionyl substituents in low-coordinate phosphorus chemistry – probing the scope Eur. J. Inorg. Chem. 2016, 3559–3573. DOI: 10.1002/ejic.201600703.
  191. A. Kyri, G. Schnakenburg, R. Streubel, A novel route to C-unsubstituted 1,2-oxaphosphetane and 1,2-oxaphospholane Complexes Chem. Commun. 2016, 52, 8593–8595. DOI: 10.1039/C6CC04667C
  192. T. Sasamori, N. Tokitoh, R. Streubel, -Electron Redox Systems of Heavier Group 15 Elements, in Organic Redox Systems, Synthesis, Properties and Applications (ed. T. Nishinaga), Wiley, Hoboken, New Jersey, 2016, 563-578. (ISBN 978-1-118-85874-5)
  193. T. Heurich, V. Nesterov, G. Schnakenburg, Z.-W. Qu, S. Grimme, K. Hazin, D. P. Gates, M. Engeser, R. Streubel, Strong evidence for a phosphanoxyl complex: formation, bonding and reactivity of ligated P-analogues of nitroxides Angew. Chem. Int. Ed. 2016, 55, 14439-14443. DOI: 10.1002/anie.201608169 and 10.1002/ange.201608169
  194. I. Begum, G. Schnakenburg, R. Streubel, On route to C4/C5 P-bifunctional 1,3-thiazole-based carbenes Eur. J. Inorg. Chem. 2016, 5265–5270. DOI: 10.1002/ejic.201600911
  195. A. W. Kyri, R. Kunzmann, G. Schnakenburg, Z.-W. Qu, S. Grimme, R. Streubel, Synthesis of a monomolecular anionic FLP complex Chem. Commun. 2016, 52, 13361 – 13364. DOI: 10.1039/c6cc07081g
  196. P. Malik, G. Schnakenburg, A. Espinosa Ferao, R. Streubel, Cycloaddition of P-C single bonds? Stereoselective formation of novel benzo-1,3,6,2-trioxaphosphepine complexes via a ditopic van der Waals complex Angew. Chem. Int. Ed. 2016, 55, 12693-12697. DOI: 10.1002/anie.201606264 and 10.1002/ange.201606264
  197. A. Espinosa Ferao, R. Streubel, Thiaphosphiranes and their complexes: systematic study on ring strain and ring cleavage reactions Inorg. Chem. 2016, 55, 9611-9619. DOI: 10.1021/acs.inorgchem.6b01322
  198. A. Kyri, P. K. Majhi, T. Sasamori, T. Agou, V. Nesterov, J.-D. Guo, S. Nagase, N. Tokitoh, R. Streubel, Synthesis of 1-Aryl-2,2-chlorosilylphosphasilene Coordinated by a N-Heterocyclic Carbene Molecules 2016, 21, 1309-1312. DOI: 10.3390/molecules21101309
  199. C. Murcia, G. Schnakenburg, A. Bauzá, A. Frontera, R. Streubel, Ambiguous reactivity of Li/Cl phosphinidenoid complexes under redox conditions – a novel dichotomy in phosphorus chemistry Chem. Commun. 2017, 53, 933 - 936. DOI: 10.1039/c6cc09620d
  200. C. Murcia, G. Schnakenburg, R. Streubel, Study on the acid-induced ring-expansion of an oxaphosphirane complex with an electron-withdrawing C-substituent Austr. J. Chem. 2017, 70, 442-446. DOI: org/10.1071/CH16609
  201. P. K. Majhi, J. M. Villalba Franco, G. Schnakenburg, R. Streubel, Synthesis, structure and first reactivity studies of functional (phosphinoamino)boranes Eur. J. Inorg. Chem. 2017, 910-914. DOI: 10.1002/ejic.201601366
  202. A. W. Kyri. P. Brehm, G. Schnakenburg, R. Streubel, Ring opening of a sterically crowded 1,2-oxaphosphetane complex Dalton Trans. 2017, 46, 2904-2909. DOI: 10.1039/C7DT00136C
  203. A. Espinosa Ferao, R. Streubel, Coordination of N2 and other small molecules to the phosphorus center of RPW(CO)5 - A theoretical study on the Janus facets of the stabilization/activation problem Chem. Eur. J. 2017, 23, 8632-8643. DOI: org/10.1002/chem.201700524
  204. R. Streubel, A. Schmer, A. W. Kyri, G. Schnakenburg, 1,1′-Bifunctional Aminophosphane Complexes via N–H Bond Insertions of a Li/Cl Phosphinidenoid Complex and First Studies on N/P Mono Functionalizations Organometallics 2017, 36, 1488-1495. DOI: 10.1021/acs.organomet.7b00073
  205. A. Espinosa Ferao, R. Streubel, A computational study on the stability of oxaphosphirane rings towards closed-shell valence isomerization, Eur. J. Inorg. Chem. 2017, 2707-2712. DOI: org/10.1002/ejic.201700177
  206. A. Koner, G. Pfeifer, Z. Kelemen, G. Schnakenburg, L. Nyulászi, T. Sasamori, R. Streubel, 1,4-Diphosphinines from imidazole-2-thiones Angew. Chem. Int. Ed. 2017, 56, 9231-9235. DOI: org/10.1002/anie.201704070 and DOI: org/10.1002/ange.201704070
  207. T. Heurich, Z.-W. Qu, G. Schnakenburg, Y. Nejaty Jahromy, O. Schiemann, S. Grimme, R. Streubel, Chemistry of thermally generated transient phosphanoxyl complexes Organometallics 2017, 36, 2877-2883. DOI: 10.1021/acs.organomet.7b00347
  208. R. Streubel, P. Junker, G. Schnakenburg, Synthesis of P-CPh3 substituted spirooxaphosphirane complexes: Steric effects dominate the product formation Organometallics 2017, 36, 2952-2955. DOI: 10.1021/acs.organomet.7b00404
  209. A. Koner, S. C. Serin, G. Schnakenburg, B. O. Patrick, D. P. Gates, R. Streubel, Exploring the chemistry of backbone-substituted amino(chloro)phosphanyl-imidazole-2-thiones Dalton Trans. 2017, 46, 10504-10514. DOI: 10.1039/C7DT01859B
  210. A. W. Kyri, G. Schnakenburg, R. Streubel, Acid-induced Reactions of 1,2-Oxaphosphetane Complexes, Organometallics 2017, 36, 3605-3612. DOI: 10.1021/acs.organomet.7b00520
  211. A. Koner, S. Sauerbrey, G. Schnakenburg, A. Bauzá, A. Frontera, R. Streubel, Synthesis and reactivity of imidazole-2-thione-based tricyclic 1,4-dihydro-1,4-diphosphinines, Eur. J. Inorg. Chem. 2018, 904-916. DOI:10.1002/ejic.201701338
  212. A. Koner, Z. Kelemen, G. Schnakenburg, L. Nyulàszi, R. Streubel, 1,4-Additions of tricyclic 1,4-diphosphinines –a novel system to study s-bond activation and p-p dispersion interactions, Chem. Commun. 2018, 54, 1182-1184. DOI: 10.1039/C7CC09349G
  213. T. Heurich, Z.-W. Qu,R. Kunzmann, G. Schnakenburg, M. Engeser, S. Nožinović, R.Streubel, Styrene polymerization under ambient conditionsusing a transient 1,3,2-diazaphos-pholane-2-oxyl complex, Chem. Eur. J. 2018, 24, 6473-6478. DOI: 10.1002/chem.201800413
  214. A. Kyri, F. Gleim, D. Becker, G. Schnakenburg, A. Espinosa Ferao, R. Streubel, “Low-coordinate” 1,2-oxaphosphetanes–a new opportunity in coordination andmain group chemistryChem. Commun. 2018, 54, 7123-7126. DOI: org/10.1039/C8CC02963F
  215. J. Faßbender, N. Künemund, G. Schnakenburg, A. Espinosa Ferao, R. Streubel, Epoxide-like chemistry: on the stereo-and regioselective ring opening of an oxaphosphirane complex, Organometallics 2018, 37, 1331-1336. DOI: 10.1021/acs.organomet.8b00116
  216. J. Faßbender, G. Schnakenburg, A. Espinosa Ferao, R. Streubel, Effects of diminished steric protection at phosphorus on stability and reactivity of oxaphosphirane complexes, Dalton Trans. 2018, 47, 9347-9354. DOI: 10.1039/c8dt01979g
  217. A. Koner, M. Kunz, G. Schnakenburg,R. Streubel, The quest for twofold reductive P-C bond cleavage of P-Ph substituted 1,4-dihydro-1,4-diphosphinines derivatives Eur. J. Inorg. Chem. 2018, 3778-3784. DOI: 10.1002/ejic.201800753
  218. T. Heurich, N. R. Naz, Z.-W. Qu, G. Schnakenburg, R. Streubel, Formationand reactivity of transient phosphanoxyl manganese complexes, Organometallics 2018, 37, 3670-3677.
  219. I. Begum, G. Schnakenburg, Z. Kelemen, L. Nyulászi, R. T. Boeré, R. Streubel, Expanding the chemistry of ring-fused 1,4-diphosphinines by stable mono anion formation, Chem. Commun. 2018, 54, 13555-13558. DOI: 10.1039/c8cc08158a
  220. A. Schmer, T. Terschüren, G. Schnakenburg, A. Espinosa Ferao, R. Streubel, Access to 1,1’-bifunctional phosphane iron(0) complexes via P-N bond forming reactions and selective P-functionalizations, Eur. J. Inorg. Chem. 2018, accepted. DOI: 10.1002/ejic.201801065
  221. J. Faßbender, G. Schnakenburg, D. P. Gates, A. Espinosa Ferao, R. Streubel, Unconventional ionic ring-deconstruction pathways of a three-membered heterocycle, Chem. Commun. 2018, 54, 7123-7126. DOI: org/10.1039/C8cc08713j
  222. A. Rey, A. Espinosa Ferao, R. Streubel, Quantum chemical calculations on CHOP derivatives –spanning the chemical space of phosphinidenes, phosphaketenes, oxaphosphirenes and COP-isomers, Molecules 2018, 23, 3341-3357. DOI: 10.3390/molecules23123341
  223. A. Schmer, N. Volk, G. Schnakenburg, A. Espinosa Ferao, R. Streubel, Access and unprecedented reaction pathways of Li/Cl phosphinidenoid iron(0) complexes, Dalton Trans. 2019, 48, 339 -345. DOI: 10.1039/c8dt04417a
  224. A. Kyri, F. Gleim, D. Becker, G. Schnakenburg, A. Espinosa Ferao, R. Streubel, Synthesis of free and ligated 1,2-thiaphosphetanes–expanding the pool of strained P-ligands, Chem. Commun. 2019, 55, 1615-1618.DOI: 10.1039/c8cc09892a
  225. D. Gudat, A. Orthaber, C. Slootweg, R. Streubel, Phosphorus Special Issue in Honor of Koop Lammertsma and Edgar Niecke, Eur. J. Inorg. Chem. 2019,1437-1439. DOI: 10.1002/ejic.201900192
  226. A. Schmer, T. Terschüren, G. Schnakenburg, A. Espinosa Ferao, R. Streubel, Access to 1,1'-Bifunctional Phosphane Iron(0) Complexes via P-N Bond-Forming Reactions and Selective P-Functionalizations, Eur. J. Inorg. Chem. 2019, 1604-1611. DOI:10.1002/ejic.201801065
  227. I. Begum, G. Schnakenburg, Z. Han, A. Franconetti, A.Frontera, D. P. Gates, R. Streubel, From P-functional thiazol-2-thione derivatives to phosphaalkenes Eur. J. Inorg. Chem. 2019, 1697-1705. DOI:10.1002/ejic.201900031
  228. A. Koner, B. M. Gabidullin, Z. Kelemen, L. Nyulászi, G.Nikonov, R.Streubel, 7-Metalla-1,4-diphosphanorbornadienes: cycloaddition of monovalent group 13 NacNac complexes to a stable 1,4-diphosphinine, Dalton Trans. 2019, 48, 8248 - 8253. DOI: 10.1039/c9dt01425j
  229. A. A. Khan, P. Junker, G. Schnakenburg, A. Espinosa Ferao, R. Streubel, Competitive or sequential reaction of an electrophilic terminal phosphinidene metal(0) complex with allyl halides? [2+1]-Cycloaddition vs C-X bond insertion, Chem. Commun. 2019, 55, 9987 - 9990. DOI: 10.1039/C9CC05328J
  230. N. Rauf Naz, G. Schnakenburg, A. Mikeházi, Z. Kelemen, L. Nyulászi, R. T. Boeré, R. Streubel, Janus bis(NHCs) tuned by heteroatom-bridge oxidation states, Chem. Commun. 2020. DOI: 10.1039/C9CC08468A
  231. I. Begum, G. Schnakenburg, R. Streubel, Synthesis and oxidation reactions of thiazol‐2‐thione-fused 1,4‐dihydro‐1,4‐diphosphinines, Chem.Select. 2020, 5, 5959-5964. DOI: 10.1002/slct.202000946
  232. A. Espinosa Fearo, R. Streubel, 1,2-Thiaphosphetanes: The quest for Wittig-type ring cleavage, rearrangement and sulfur atom transfer,Inorg. Chem. 2020, 59, 3110-3117. DOI: 10.1021/acs.inorgchem.9b03471
  233. R. Kunzmann, Y. Omatsu, G. Schnakenburg, A.Espinosa Ferao, T. Yanagisawa, N. Tokitoh, R. Streubel, A synthon for unknown 1,3-zwitterions? - A K/OR phosphinidenoid complex with an additional Si-Cl function, Chem. Commun. 2020, 56, 3899-3902. DOI: 10.1039/d0cc00024h
  234. P. Junker, J. M. Villalba Franco, G. Schnakenburg, V. Nesterov, R. Boeré, Z.-W. Qu, R. Streubel, Formation and properties of phosphaquinomethane tungsten(0) complexes – isolation and conversion of primary radical coupling products, Dalton Trans. 2020, 49, 13544-13548. DOI: 10.1039/d0dt03089a
  235. I. Begum, T. Kalisch, G. Schnakenburg, Z. Kelemen, L. Nyulaszi, R. Streubel, [4+2]-Cycloadditions of a thiazol-based tricyclic 1,4-diphosphinine and a new easy 1,4-diphosphinine protection deprotection strategyDalton Trans. 2020, 49, 12776 – 12779. DOI: 10.1039/d0dt02529a
  236. A. Gese, M. Akter, G. Schnakenburg, A. Espinosa Ferao, R. Streubel, P-Functional tetrathiafulvalenes from 1,3-dithiole-2-thiones? New J. Chem. 2020, 44, 17122–17128. DOI: 10.1039/d0nj02984j
  237. A. Espinosa Ferao, A. García Alcaraz, S. Zaragoza Noguera, R. Streubel, Terminal phosphinidene complex adducts with neutral and anionic O-donors and halides, and the search for a differentiating bonding desriptor, Inorg. Chem. 2020, 59, 12829-12841. DOI: 10.1021/acs.inorgchem.0c01874
  238. P. Junker, Z-W. Qu, T. Kalisch, G. Schnakenburg, A. Espinosa Ferao, R. Streubel, A case study on the conversion of Li/Cl phosphinidenoid into phosphinidene complexes, 2020, submitted.
  239. N. Rauf Naz, G. Schnakenburg, Z. Kelemen, D. Gal, L. Nyulászi, R. T. Boeré, R. Streubel, A rigid anionic Janus bis(NHC) – new opportunities in NHC chemistry, Dalton Trans. 2021, 50, 689-695. DOI: 10.1039/dt0dt03915b
  240. A. Espinosa Ferao, A. Rey Planells, R. Streubel, Between oxirane and phosphirane: the spring loaded oxaphosphirane ring Eur. J. Inorg. Chem. 2021, 348-353. DOI: 10.1002/ejic.202000881
  241. R. Streubel, N. Volk, G. Schnakenburg, A. Garcia Alcaraz, A. Espinosa Ferao, Synthesis and reactions of the first oxaphosphirane iron complexes, Eur. J. Inorg. Chem. 2020, 252-257. DOI: 10.1002/ejic.202000812
  242. N. Volk, P. Malik, A. Garcia Alcaraz, A. Espinosa Ferao, R. Streubel, Chemistry of oxaphosphirane complexes, Coord. Chem. Rev, 2021, 437, 213818. DOI: 10,1016/j.ccr.2021.213818
  243. A. Schmer, A. Bauza, G. Schnakenburg, A. Frontera, R. Streubel, Molecular 1,1’-bifunctional mixed-valence P-P compounds, enabled through metal complexation, Dalton Trans. 2021, 50, 2131-2137. DOI: 10.1039/d0dt04070c
  244. A. Schmer, P.Junger, A. Espinosa Ferao, R. Streubel, M/X Phosphinidenoid Metal Complex Chemistry, Acc. Chem. Res. 2021, 54, 1754-1765. DOI: 10.1021/acs.accounts.1c00017
  245. P. Junger, A. Rey Planells, A. Espinosa Ferao, R. Streubel, Analysis of non-innocence of phosphaquinodimethane ligands when charge and aromaticity come into play, Chem. Eur. J. 2021, DOI: 10.1002/chem.202100420
  246. A. Garcia Alcaraz, A. Espinosa Ferao, R. Streubel,Azaphosphiridines: Challenges and perespectives, Dalton Trans. 2021, 50, 9345-9366. DOI: 10.1039/d1dt01624eA. Gese, S. Kermanshahian, G. Schnakenburg, Z. Kelemen, L. Nyulaszi, A. Espinosa Ferao, R. Streubel,Towards a 1,4-diphosphinine-based molecular CPS-ternary compound, Inorg. Chem. 2021, DOI: org/10.1021/acs.inorgchem.1c01463
  247. D. Welideniya, R. Ramachandran, T. Kalisch, R. Streubel,New frontiers: 1,4-diphosphinines and P-bridged bis(NHCs) 2021, DOI: org/10.1021/acs.inorgchem.1c01463
  248. A. Schmer, D. Welideniya, T. Terschüren, G. Schnakenburg, J. Daniels, A. Bauza, A. Frontera, R. Streubel, A homonuclear π-system with a singlet carbene-type α and a nucleophilic β phosphorus - first use in P-heterocyclic synthesis, Dalton Trans. 2021, 50, 17892-17896. DOI: 10.1039/D1DT03350F
  249. A. Schmer, A. Garcia Alcaraz, G. Schnakenburg, A. Espinosa Ferao, R. Streubel, Azadiphosphiridine complexes – with or without a planar nitrogen geometry? – and the quest of the P-to-P’ haptotropic metal shift, Dalton Trans.2022,51,3275-3279. DOI: 10.1039/D1DT04252A
  250. M. Ramachandran, G. Schnakenburg, M. Majumdar, Z. Kelemen, D. Gál, L. Nyulászi, R. T. Boeré, R. Streubel, Reversible redox chemistry of anionic imidazole-2-thione-fused 1,4-dihydro-1,4-diphosphinines, Inorg. Chem. 2022, accepted. DOI: 10.1021/acs.inorgchem.1c03620
  251. P. Brehm, A. Müller-Feyen, G. Schnakenburg, R. Streubel, 1,3,2-Diheterophospholane complexes: access to new tuneable precursors of phosphanoxyl complexes and P-functional polymers, Dalton Trans. 2022, 51, 4400 - 4405. DOI: 10.1039/d2dt00027j.
  252. P. Brehm, A. Frontera, R. Streubel, On metal coordination of neutral open-shell P-ligands focusing on phosphanoxyls, their electron residence and reactivity, Chem. Commun. 2022, accepted. DOI: 10.1039/D2CC01302A.
  253. Z.-W. Qu, H. Zhu, R. Streubel, S. Grimme, Catalyst-free CO2 Hydrogenation with BH3NH3 in Water: DFT Mechanistic Insights, Phys. Chem. Chem. Phys., 2022, 24, 14159-14164. DOI: 10.1039/d2cp00590e.
  254. Z.-W. Qu, H. Zhu, R. Streubel, S. Grimme, C-H Deprotonation and C=C Hydrogenation of N-heterocyclic Olefin with Calcium Hydride Complexes: Terminal Ca-H bond versus Cooperative Ca-H-Ca Bridge, Chem. Cat. Chem., 2022, 14. DOI: 10.1002/cctc.202200508.
  255. T. Terschüren, P. Junker, A. Schmer, A. Espinosa Ferao, R. Streubel, Regioselective N- versus P-deprotonation of aminophosphane tungsten(0) complexes, Organics, 2021, 3, 161-172. DOI: 10.3390/org3030013.
  256. F. Gleim, A. Garcia Alcaraz, G. Schnakenburg, A. Espinosa Ferao, R. Streubel, 1,2σ3λ3-Oxaphosphetanes and their P-chalcogenides – a combined experimental and theoretical study, Molecules 2022, 27, 3345-3357. DOI: 10.3390/molecules27103345.
  257. Z.-W. Qu, H. Zhu, R. Streubel, S. Grimme, Catalytic Isomerization of Unprotected Mesoionic N-Heterocyclic Olefins and Their Lewis Adducts,Eur. J. Org. Chem., 2022, 1-5. DOI: 10.1002/ejoc.202200539.
  258. J. Faßbender, N. Volk, A. García Alcaraz, S. Balasubramaniam, A. Espinosa Ferao, R. Streubel, The quest for unligated oxaphosphiranes with phosphorus in different coordination numbers, Chem. Commun., 2023, 1285-1288. DOI: 10.1039/D2CC05730A.
  259. Z.-W. Qu, H. Zhu, R. Streubel, S. Grimme, Organo-Group 2 Metal Mediated Nucleophilic Alkylation of Benzene: Crucial Role of Strong Cation-π Interaction, ACS Catalysis, 2023, 13, 1686–1692. DOI: 10.1021/acscatal.2c05755
  260. H. Zhu, Z.-W. Qu, P. Brehm, S. Grimme, R. Streubel, Design of Transition Metal Complexes containing a P-E radical motif, Dalton Trans, 2023, 52, 2356-2362. DOI: 10.1039/D2DT04149A

  261. A. A. Khan, T. Kalisch, A. Espinosa Ferao, R. Streubel, Dehydrogenation reaction of triethylamine by an electrophilic terminal phosphinidene complex, Dalton Trans. 2023, 52, 3275–3278. DOI: 10.1039/D3DT00300K

  262. D. Biskup, G. Schnakenburg, R. T. Boeré, A. Espinosa Ferao, R. K. Streubel, Challenging an old paradigm: coordination and transition metal-like chemistry of a neutral nonmetal ligand center, Nat. Commun. 2023, 14, 6456. DOI: 10.1038/s41467-023-42127-3

  263. D. Biskup, T. Bergmann, G. Schnakenburg, R. Streubel, Synthesis of the first 1-aza-2-phospha-acenaphtene complex, RSC Advances 2023, 13, 21313. DOI: 10.1039/D3RA04352E

  264. S. Kermanshahian, T. Kalisch, G. Schnakenburg, Z. Kelemen, L. Nyulászi, R. T. Boeré, R. Streubel, Access to and reactions of a P-functional 1,4-dihydro-1,4-diphosphinine being fused to two TTF units, Dalton Trans. 2023, 52, 9356-9367. DOI: 10.1039/D3DT00985H

  265. M. R. K. Ramachandran, P. C. Brehm, G. Schnakenburg, T. Sasamori, R. T. Boeré, R. Streubel, P-centered redox reactions of a 1,4-dihydro-1,4-phosphasiline, Dalton Trans. 2023, 52, 7948–7956. DOI: 10.1039/d3dt00850a

  266. D. Biskup, G. Schnakenburg, R. T. Boeré, A. Espinosa Ferao, R. Streubel, A novel access to phosphanylidene-phosphorane complexes via P-donor substitution and a detailed bonding analysis Dalton Trans. 2023, 52, 13781. DOI: 10.1039/d3dt02304d

  267. M. R. K. Ramachandran, P. C. Brehm, T. Sasamori, R. Streubel, Unlocking some Si-centered reactivity of a 4,4’-dichloro-1,4-dihydro-1,4-phosphasiline, Eur. J. Inorg. Chem. 2024, 27, e2023005

  268. D. Biskup, G. Schnakenburg, A. Espinosa Ferao, R. Streubel, Access to PH-containing donor-stabilized phosphenium complexes Dalton Trans. 2024, 53, 2517–2525. DOI: 10.1039/D3DT03869F

  269. F. Gleim, G. Schnakenburg, A. Espinosa Ferao, R. Streubel, Arbuzov meets 1,2-oxaphosphetanes: transient 1,2-oxaphosphetan-2-iums as entry point to beta-halo phosphane oxides and P-containing oligomers Chem. Commun. 2024, 60, 2625-2628, DOI: 10.1039/D4CC00254G

  270. D. Biskup, G. Schnakenburg, A. Espinosa Ferao, R. Streubel, A metal and a metalloid Lewis acid bridged by a phosphinidene, 2024, submitted.

  271. M. R. K. Ramachandran, S. Karwasara, H. Zhu, G. Schnakenburg, R. Streubel, Synthesis of tricyclic 1,4-dihydro-1,4-phosphagermines, 2024, under revision.

  272. T. Terschüren, G. Schnakenburg, R. Streubel, Application of phosphorus-bridged rigid, bent bis(NHCs) as dipodal and tripodal ligands in main group and transition metal chemistry Dalton Trans. 2024, 53, 5043-5050. DOI: 10.1039/d4dt00378k

  273. A. Rey Planells, A. Espinosa Ferao, R. Streubel, A. Frontera, Internal Coulombic Assistance in Intermolecular Frustrated Lewis Pair Activation of Dihydrogen New. J. Chem. 2024, 48, 4675-4679. DOI: 10.1039/d4nj00523f

  274. T. Kalisch, P. C. Brehm, A. Frontera, R. Streubel, Tricyclic 1,4-diphosphinines: Local vs. Global Aromaticity, 2024, submitted.

  275. S. Karwasara, M. R. K. Ramachandran, P. C. Brehm, G. Schnakenburg, T. Sasamori, R. T. Boeré, R. Streubel, On a 1,4-phosphagermine, its anion and germanium-centered radical, 2024, to be submitted.